Noncovalently galactose imprinted polymer for the recognition of different saccharides

Basit Öğe Kaydı
dc.contributor.authorOkutucu, Burcu
dc.contributor.authorOenal, Secil
dc.contributor.authorTelefoncu, Azmi
dc.date.accessioned2019-10-27T20:51:56Z
dc.date.available2019-10-27T20:51:56Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractMolecularly imprinted polymers (MIPs) represent a new class of materials possessing high selectivity and affinity for the target molecule. The main goal of this study was to prepare a galactose imprinted polymer and its potential application for the recognition of different saccharides. The selectivity of galactose imprinted polymer for several saccharides: glucose, mannose, fructose, maltose, lactose, Sucrose and raffinose was investigated. Macroporous polymer was prepared utilizing ethyleneglycoldimethacrylate as a crosslinking agent, in the presence of galactose as a template molecule with acrylamide as a functional monomer. After the synthesis of polymer, galactose was removed by methanol:acetic acid washing. The selectivity of galactose imprinted polymer for other saccharides was utilized by batch rebinding assay. The arrangement of functional groups within cavities versus shape selectivity is discussed. The results showed the orientation of the functional groups was the dominating factor for the selectivity of galactose that, imprinted polymer. The dissociation constants of polymer were determined by Scatchard analysis. (c) 2009 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.talanta.2009.01.047en_US
dc.identifier.endpage1193en_US
dc.identifier.issn0039-9140
dc.identifier.issue3en_US
dc.identifier.pmid19269492en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1190en_US
dc.identifier.urihttps://doi.org/10.1016/j.talanta.2009.01.047
dc.identifier.urihttps://hdl.handle.net/11454/43170
dc.identifier.volume78en_US
dc.identifier.wosWOS:000264976600087en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofTalantaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMolecular imprintingen_US
dc.subjectMolecularly imprinted polymeren_US
dc.subjectGalactose imprintingen_US
dc.subjectCarbohydrateen_US
dc.subjectShape selectivityen_US
dc.titleNoncovalently galactose imprinted polymer for the recognition of different saccharidesen_US
dc.typeArticleen_US

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