Palladium(II) complexes containing 2,6-bis(imino)pyridines: Synthesis, characterization, thermal study, and catalytic activity in suzuki reactions

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dc.contributor.authorDayan O.
dc.contributor.authorDogan F.
dc.contributor.authorKaya I.
dc.contributor.authorCetinkaya B.
dc.date.accessioned2019-10-26T22:37:13Z
dc.date.available2019-10-26T22:37:13Z
dc.date.issued2010
dc.departmentEge Üniversitesien_US
dc.description.abstractA series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change ?Sz.ast;, enthalpy change ?H#, and Gibbs free energy change ?G# of the thermal decomposition were calculated by means of several methods based on the single heating rate. Copyright © Taylor & Francis Group, LLC.en_US
dc.description.sponsorship2009-16 107T808en_US
dc.description.sponsorshipThis research has been supported by The Scientific and Technical Research Council of Turkey (TUB'TAK) (Project No: 107T808) and C¸ anakkale Onsekiz Mart University Scientific Research Projects Commission (Project No: 2009-16). --en_US
dc.identifier.doi10.1080/15533174.2010.486822
dc.identifier.endpage344en_US
dc.identifier.issn1553-3174
dc.identifier.issn1553-3174en_US
dc.identifier.issue5en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage337en_US
dc.identifier.urihttps://doi.org/10.1080/15533174.2010.486822
dc.identifier.urihttps://hdl.handle.net/11454/19898
dc.identifier.volume40en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectActivation energyen_US
dc.subjectPd(II) complexesen_US
dc.subjectPyridine-2,6-diiminesen_US
dc.subjectSuzuki reactionen_US
dc.subjectThermal behavioren_US
dc.titlePalladium(II) complexes containing 2,6-bis(imino)pyridines: Synthesis, characterization, thermal study, and catalytic activity in suzuki reactionsen_US
dc.typeArticleen_US

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