Palladium(II) complexes containing 2,6-bis(imino)pyridines: Synthesis, characterization, thermal study, and catalytic activity in suzuki reactions
Küçük Resim Yok
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A series of palladium complexes: [(Pydim)PdCl](PdCl3) (Pydim (1): pyridine-2,6-diimine) have been synthesized from palladium dichloride and the corresponding pydim. The Pd (II) complexes have been used as catalyst in the Suzuki reaction of aryl halides. Moreover, thermal behaviors of palladium complexes have been studied in nitrogen atmosphere using TG/DTG and DTA techniques. The values of activation energy Ea, and reaction order n, the entropy change ?Sz.ast;, enthalpy change ?H#, and Gibbs free energy change ?G# of the thermal decomposition were calculated by means of several methods based on the single heating rate. Copyright © Taylor & Francis Group, LLC.
Açıklama
Anahtar Kelimeler
Activation energy, Pd(II) complexes, Pyridine-2,6-diimines, Suzuki reaction, Thermal behavior
Kaynak
Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry
WoS Q Değeri
Scopus Q Değeri
N/A
Cilt
40
Sayı
5
