Annulated N-heterocyclic carbene ligands derived from 2- methylaminopiperidine: Their complexes and catalytic applications
dc.contributor.author | Turkmen H. | |
dc.contributor.author | Pape T. | |
dc.contributor.author | Hahn F.E. | |
dc.contributor.author | Çetinkaya B. | |
dc.date.accessioned | 2019-10-27T08:36:42Z | |
dc.date.available | 2019-10-27T08:36:42Z | |
dc.date.issued | 2008 | |
dc.department | Ege Üniversitesi | en_US |
dc.description.abstract | A new type of carbene precursor, 1,5,6,7,8,8a-hexahydroimidazo[1,5-a] pyridine (1), has been prepared from 2-(aminomethyl)piperidine and N,N-dimethylformamide dimethylacetal. The reactions of three imidazolidinium salts with [Rh(acac)(COD)] and [Ir(µ-OMe)(COD)]2 were found to afford rhodium and iridium complexes of N-heterocyclic carbenes, respectively. These complexes have been tested as catalysts in the transfer hydrogenation of cyclohexanone and acetophenone using 2-propanol as hydrogen source. © 2008 American Chemical Society. | en_US |
dc.identifier.doi | 10.1021/om701105y | |
dc.identifier.endpage | 575 | en_US |
dc.identifier.issn | 0276-7333 | |
dc.identifier.issn | 0276-7333 | en_US |
dc.identifier.issue | 4 | en_US |
dc.identifier.scopusquality | Q1 | en_US |
dc.identifier.startpage | 571 | en_US |
dc.identifier.uri | https://doi.org/10.1021/om701105y | |
dc.identifier.uri | https://hdl.handle.net/11454/27427 | |
dc.identifier.volume | 27 | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.relation.ispartof | Organometallics | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.title | Annulated N-heterocyclic carbene ligands derived from 2- methylaminopiperidine: Their complexes and catalytic applications | en_US |
dc.type | Article | en_US |