Annulated N-heterocyclic carbene ligands derived from 2- methylaminopiperidine: Their complexes and catalytic applications

dc.contributor.authorTurkmen H.
dc.contributor.authorPape T.
dc.contributor.authorHahn F.E.
dc.contributor.authorÇetinkaya B.
dc.date.accessioned2019-10-27T08:36:42Z
dc.date.available2019-10-27T08:36:42Z
dc.date.issued2008
dc.departmentEge Üniversitesien_US
dc.description.abstractA new type of carbene precursor, 1,5,6,7,8,8a-hexahydroimidazo[1,5-a] pyridine (1), has been prepared from 2-(aminomethyl)piperidine and N,N-dimethylformamide dimethylacetal. The reactions of three imidazolidinium salts with [Rh(acac)(COD)] and [Ir(µ-OMe)(COD)]2 were found to afford rhodium and iridium complexes of N-heterocyclic carbenes, respectively. These complexes have been tested as catalysts in the transfer hydrogenation of cyclohexanone and acetophenone using 2-propanol as hydrogen source. © 2008 American Chemical Society.en_US
dc.identifier.doi10.1021/om701105y
dc.identifier.endpage575en_US
dc.identifier.issn0276-7333
dc.identifier.issn0276-7333en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage571en_US
dc.identifier.urihttps://doi.org/10.1021/om701105y
dc.identifier.urihttps://hdl.handle.net/11454/27427
dc.identifier.volume27en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofOrganometallicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleAnnulated N-heterocyclic carbene ligands derived from 2- methylaminopiperidine: Their complexes and catalytic applicationsen_US
dc.typeArticleen_US

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