Annulated N-heterocyclic carbene ligands derived from 2- methylaminopiperidine: Their complexes and catalytic applications
Küçük Resim Yok
Tarih
2008
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A new type of carbene precursor, 1,5,6,7,8,8a-hexahydroimidazo[1,5-a] pyridine (1), has been prepared from 2-(aminomethyl)piperidine and N,N-dimethylformamide dimethylacetal. The reactions of three imidazolidinium salts with [Rh(acac)(COD)] and [Ir(µ-OMe)(COD)]2 were found to afford rhodium and iridium complexes of N-heterocyclic carbenes, respectively. These complexes have been tested as catalysts in the transfer hydrogenation of cyclohexanone and acetophenone using 2-propanol as hydrogen source. © 2008 American Chemical Society.
Açıklama
Anahtar Kelimeler
Kaynak
Organometallics
WoS Q Değeri
Scopus Q Değeri
Q1
Cilt
27
Sayı
4
