Synthesis of a ruthenium complex bound to a polyimide matrix: Investigating the catalytic properties in a hydrosilylation reaction
| dc.contributor.author | Seçkin, Turgay | |
| dc.contributor.author | Köytepe, Süleyman | |
| dc.contributor.author | Özdemir, İsmail | |
| dc.contributor.author | Çetinkaya, Bekir | |
| dc.date.accessioned | 2020-12-01T12:18:28Z | |
| dc.date.available | 2020-12-01T12:18:28Z | |
| dc.date.issued | 2006 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | 3,6-Bis(dimethylamino)acridine(hexamethylbenzene)dichlororuthemum(Il) was used as a tricyclic heteroatomic monomer to prepare polyirnides from the corresponding dianhyrides by solution con¬densation. the ruthenium complex monomer was synthesized starting from $[RuCl_2(HMB)]_2$ and 3-6-bis(dimethylamino)acridine. the polymers had inherent viscosities of 1.77 to 2.11 and were soluble in most polar solvents. the glass transition temperatures were in the range of 204 to 298 °C and the 10% weight loss in the range of 506-626 °C, depending upon the structure of the dianhyride monomer. the catalytic activity of the polyimides tested in a hydrosilylation reaction of acetophenone was up to 90%. Leaching of ruthenium into the reaction mixture, found to be in the range of 60-75 ppm, was an indication of reduced catalyst bleeding. | en_US |
| dc.identifier.endpage | 101 | en_US |
| dc.identifier.issn | 1300-0527 | |
| dc.identifier.issn | 1303-6130 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.startpage | 93 | en_US |
| dc.identifier.uri | https://app.trdizin.gov.tr//makale/TlRNMU16RXg | |
| dc.identifier.uri | https://hdl.handle.net/11454/64488 | |
| dc.identifier.volume | 30 | en_US |
| dc.indekslendigikaynak | TR-Dizin | en_US |
| dc.language.iso | en | en_US |
| dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Mühendislik, Kimya | en_US |
| dc.title | Synthesis of a ruthenium complex bound to a polyimide matrix: Investigating the catalytic properties in a hydrosilylation reaction | en_US |
| dc.type | Article | en_US |
