(Acetonitrile){2,6-bis-[1-(2,4,6-tri-methyl-phenyl-imino)-ethyl]-pyridine} -dichlorido-ruthenium(II) dichloro-methane solvate
| dc.contributor.author | Özdemir N. | |
| dc.contributor.author | Dinçer M. | |
| dc.contributor.author | Dayan O. | |
| dc.contributor.author | Çetinkaya B. | |
| dc.date.accessioned | 2019-10-27T08:37:19Z | |
| dc.date.available | 2019-10-27T08:37:19Z | |
| dc.date.issued | 2007 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | In the title compound, [RuCl2(C2H3N)(C27H31N3)]·CH2Cl2, the Ru II ion is six-coordinated in a distorted octa-hedral arrangement, with the two Cl atoms located in the apical positions, and the pyridine (py) N atom, the two imino N atoms and the acetonitrile N atom located in the basal plane. The two equatorial Ru - Nimino distances are almost equal (mean 2.087 Å) and are substanti-ally longer than the equatorial Ru - Npy bond [1.921 (4) Å]. It is observed that the Nimino - M - Npy angle for the five-membered chelate rings of pyridine-2,6-diimine complexes is inversely related to the magnitude of the M - Npy bond. The title structure is stabilized by intra- and inter-molecular C - H?Cl hydrogen bonds, as well as by van der Waals inter-actions. © International Union of Crystallography 2007. | en_US |
| dc.identifier.doi | 10.1107/S0108270107036669 | |
| dc.identifier.endpage | m409 | en_US |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.issn | 0108-2701 | en_US |
| dc.identifier.issue | 9 | en_US |
| dc.identifier.scopusquality | N/A | en_US |
| dc.identifier.startpage | m407 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S0108270107036669 | |
| dc.identifier.uri | https://hdl.handle.net/11454/27513 | |
| dc.identifier.volume | 63 | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.relation.ispartof | Acta Crystallographica Section C: Crystal Structure Communications | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | (Acetonitrile){2,6-bis-[1-(2,4,6-tri-methyl-phenyl-imino)-ethyl]-pyridine} -dichlorido-ruthenium(II) dichloro-methane solvate | en_US |
| dc.type | Article | en_US |
