(Acetonitrile){2,6-bis-[1-(2,4,6-tri-methyl-phenyl-imino)-ethyl]-pyridine} -dichlorido-ruthenium(II) dichloro-methane solvate
Küçük Resim Yok
Tarih
2007
Yazarlar
Dergi Başlığı
Dergi ISSN
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Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In the title compound, [RuCl2(C2H3N)(C27H31N3)]·CH2Cl2, the Ru II ion is six-coordinated in a distorted octa-hedral arrangement, with the two Cl atoms located in the apical positions, and the pyridine (py) N atom, the two imino N atoms and the acetonitrile N atom located in the basal plane. The two equatorial Ru - Nimino distances are almost equal (mean 2.087 Å) and are substanti-ally longer than the equatorial Ru - Npy bond [1.921 (4) Å]. It is observed that the Nimino - M - Npy angle for the five-membered chelate rings of pyridine-2,6-diimine complexes is inversely related to the magnitude of the M - Npy bond. The title structure is stabilized by intra- and inter-molecular C - H?Cl hydrogen bonds, as well as by van der Waals inter-actions. © International Union of Crystallography 2007.
Açıklama
Anahtar Kelimeler
Kaynak
Acta Crystallographica Section C: Crystal Structure Communications
WoS Q Değeri
Scopus Q Değeri
N/A
Cilt
63
Sayı
9
