Metal-organic framework functionalized with deep eutectic solvent for solid-phase extraction of Rhodamine 6G in water and cosmetic products

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dc.authorscopusid57197774524
dc.authorscopusid56322932500
dc.authorscopusid7006488616
dc.contributor.authorÖzalp, Özgür
dc.contributor.authorGümüş, Zinar Pınar
dc.contributor.authorSoylak, Mustafa
dc.date.accessioned2024-08-25T18:47:30Z
dc.date.available2024-08-25T18:47:30Z
dc.date.issued2023
dc.departmentEge Üniversitesien_US
dc.description.abstractAn NH2-MIL-53(Al)-DES(ChCl-Urea) nanocomposite was synthesized for extraction and determination of Rhodamine (Rh) 6G from environmental and cosmetic samples. The deep eutectic solvent (DES) was prepared by mixing choline chloride and urea in a mole ratio of 1:2. NH2-MIL-53(Al)-DES(ChCl-Urea) nanocomposite was synthesized using the impregnation method at a ratio of 60:40 (w/w). The optimum conditions were determined after NH2-MIL-53(Al)-DES(ChCl-Urea) characterization was performed. The optimum conditions were determined as pH 8, adsorbent amount of 15 mg, total adsorption-desorption time of 6 min, and enrichment factor of 20. The recovery values of the solid-phase extraction method for water and cosmetic samples under optimum conditions were between 95% and 106%. NH2-MIL-53(Al)-DES(ChCl-Urea) nanocomposite was an economically advantageous adsorbent because of its reusability of 15 times. All analyses were performed using the ultraviolet-visible spectrophotometer. The linear range, limit of detection, and limit of quantification of the method were 100-1000, 9.80, and 32.68 & mu;g/L, respectively. The obtained results showed that the synthesized nanocomposite is a suitable adsorbent for the determination of Rh 6G in water and cosmetic samples. The real sample applications were verified with the high-performance liquid chromatography system.en_US
dc.description.sponsorshipTUBITAK-2247/A-National Outstanding Researchers Program [121C287]; Scientific Research Projects of Erciyes University [FDK-2022-12233]en_US
dc.description.sponsorshipTUBITAK-2247/A-National Outstanding Researchers Program, Grant/Award Number: 121C287; Scientific Research Projects of Erciyes University, Grant/Award Number: FDK-2022-12233en_US
dc.identifier.doi10.1002/jssc.202300190
dc.identifier.issn1615-9306
dc.identifier.issn1615-9314
dc.identifier.pmid37496320en_US
dc.identifier.scopus2-s2.0-85165876557en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/jssc.202300190
dc.identifier.urihttps://hdl.handle.net/11454/101927
dc.identifier.wosWOS:001036333700001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofJournal of Separation Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240825_Gen_US
dc.subjectdeep eutectic solventsen_US
dc.subjectmetal-organic frameworksen_US
dc.subjectRhodamine 6Gen_US
dc.subjectsolid-phase extractionen_US
dc.subjectPerformance Liquid-Chromatographyen_US
dc.subjectTrace Determinationen_US
dc.subjectOxide Nanoparticlesen_US
dc.subjectMalachite Greenen_US
dc.subjectCompositeen_US
dc.subjectRemovalen_US
dc.subjectDyesen_US
dc.subjectSpectrophotometryen_US
dc.subjectMicroextractionen_US
dc.subjectFabricationen_US
dc.titleMetal-organic framework functionalized with deep eutectic solvent for solid-phase extraction of Rhodamine 6G in water and cosmetic productsen_US
dc.typeArticleen_US

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