Dichloro[(1E,1 ' E)-1,1 '-(pyridine-2,6-diyl)diethanone bis (O-methyloxime)-kappa(3) N-1, N-2, N-6] copper(II)

dc.contributor.authorOzdemir, Namik
dc.contributor.authorDincer, Muharrem
dc.contributor.authorDayan, Osman
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T19:17:47Z
dc.date.available2019-10-27T19:17:47Z
dc.date.issued2006
dc.departmentEge Üniversitesien_US
dc.description.abstractIn the title compound, [CuCl2(C11H15N3O2)], the Cu-II ion is five-coordinated in a strongly distorted trigonal-bipyramidal arrangement, with the two methyloxime N atoms located in the apical positions, and the pyridine N and the Cl atoms located in the basal plane. The two axial Cu-N distances are almost equal (mean 2.098 angstrom) and are substantially longer than the equatorial Cu-N bond [1.9757 (15) angstrom]. It is observed that the N(oxime)-M-N(pyridine) bond angle for five-membered chelate rings of 2,6-diacetylpyridine dioxime complexes is inversely related to the magnitude of the M N( pyridine) bond. The structure is stabilized by intra- and intermolecular C-H center dot center dot center dot Cl hydrogen bonds which involve the methyl H atoms, except for one of the two acetylmethyl groups.en_US
dc.identifier.doi10.1107/S010827010601969Xen_US
dc.identifier.endpageM318en_US
dc.identifier.issn0108-2701
dc.identifier.pmid16823201en_US
dc.identifier.startpageM315en_US
dc.identifier.urihttps://doi.org/10.1107/S010827010601969X
dc.identifier.urihttps://hdl.handle.net/11454/38475
dc.identifier.volume62en_US
dc.identifier.wosWOS:000238803100018en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherBlackwell Publishingen_US
dc.relation.ispartofActa Crystallographica Section C-Crystal Structure Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleDichloro[(1E,1 ' E)-1,1 '-(pyridine-2,6-diyl)diethanone bis (O-methyloxime)-kappa(3) N-1, N-2, N-6] copper(II)en_US
dc.typeArticleen_US

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