Dichloro[(1E,1 ' E)-1,1 '-(pyridine-2,6-diyl)diethanone bis (O-methyloxime)-kappa(3) N-1, N-2, N-6] copper(II)
| dc.contributor.author | Ozdemir, Namik | |
| dc.contributor.author | Dincer, Muharrem | |
| dc.contributor.author | Dayan, Osman | |
| dc.contributor.author | Cetinkaya, Bekir | |
| dc.date.accessioned | 2019-10-27T19:17:47Z | |
| dc.date.available | 2019-10-27T19:17:47Z | |
| dc.date.issued | 2006 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | In the title compound, [CuCl2(C11H15N3O2)], the Cu-II ion is five-coordinated in a strongly distorted trigonal-bipyramidal arrangement, with the two methyloxime N atoms located in the apical positions, and the pyridine N and the Cl atoms located in the basal plane. The two axial Cu-N distances are almost equal (mean 2.098 angstrom) and are substantially longer than the equatorial Cu-N bond [1.9757 (15) angstrom]. It is observed that the N(oxime)-M-N(pyridine) bond angle for five-membered chelate rings of 2,6-diacetylpyridine dioxime complexes is inversely related to the magnitude of the M N( pyridine) bond. The structure is stabilized by intra- and intermolecular C-H center dot center dot center dot Cl hydrogen bonds which involve the methyl H atoms, except for one of the two acetylmethyl groups. | en_US |
| dc.identifier.doi | 10.1107/S010827010601969X | en_US |
| dc.identifier.endpage | M318 | en_US |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.pmid | 16823201 | en_US |
| dc.identifier.startpage | M315 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S010827010601969X | |
| dc.identifier.uri | https://hdl.handle.net/11454/38475 | |
| dc.identifier.volume | 62 | en_US |
| dc.identifier.wos | WOS:000238803100018 | en_US |
| dc.identifier.wosquality | N/A | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | PubMed | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Blackwell Publishing | en_US |
| dc.relation.ispartof | Acta Crystallographica Section C-Crystal Structure Communications | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.title | Dichloro[(1E,1 ' E)-1,1 '-(pyridine-2,6-diyl)diethanone bis (O-methyloxime)-kappa(3) N-1, N-2, N-6] copper(II) | en_US |
| dc.type | Article | en_US |
