Aqueous-phase Suzuki–Miyaura cross-coupling reactions catalyzed by Pd-NHC complexes

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dc.contributor.authorTürkmen H.
dc.contributor.authorCan R.
dc.contributor.authorÇetinkaya B.
dc.date.accessioned2019-10-27T08:35:34Z
dc.date.available2019-10-27T08:35:34Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractCleavage reactions of [PdBr2(NHC)]2 with two equiv. of pyridine derivatives (L), having one or two carboxylic acid groups [L = NC5H4-2-COOH, NC5H4-3-COOH, NC5H4-4-COOH, or NC5H3-2,6-(COOH)2 in chloroform or DMSO, respectively, afforded the monomeric mixed ligand complexes trans-[PdBr2(NHC)L] (1–4) which, due to deprotonation of the carboxylic acid functionality, are water soluble in KOH. The catalytic activity of complexes 1–4 in aqueous Suzuki–Miyaura cross-coupling reactions were evaluated and compared. The dicarboxylic functionality enhances the catalyst reactivity and stability and the carboxylate derived from 4 could be easily recovered and reused for several cycles under the mild reaction conditions. © 2009 The Royal Society of Chemistry.en_US
dc.identifier.doi10.1039/b907032j
dc.identifier.endpage7044en_US
dc.identifier.issn1477-9226
dc.identifier.issn1477-9226en_US
dc.identifier.issue35en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage7039en_US
dc.identifier.urihttps://doi.org/10.1039/b907032j
dc.identifier.urihttps://hdl.handle.net/11454/27258
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofJournal of the Chemical Society. Dalton Transactionsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleAqueous-phase Suzuki–Miyaura cross-coupling reactions catalyzed by Pd-NHC complexesen_US
dc.typeArticleen_US

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