Aqueous-phase Suzuki–Miyaura cross-coupling reactions catalyzed by Pd-NHC complexes
Küçük Resim Yok
Tarih
2009
Yazarlar
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Dergi ISSN
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Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Cleavage reactions of [PdBr2(NHC)]2 with two equiv. of pyridine derivatives (L), having one or two carboxylic acid groups [L = NC5H4-2-COOH, NC5H4-3-COOH, NC5H4-4-COOH, or NC5H3-2,6-(COOH)2 in chloroform or DMSO, respectively, afforded the monomeric mixed ligand complexes trans-[PdBr2(NHC)L] (1–4) which, due to deprotonation of the carboxylic acid functionality, are water soluble in KOH. The catalytic activity of complexes 1–4 in aqueous Suzuki–Miyaura cross-coupling reactions were evaluated and compared. The dicarboxylic functionality enhances the catalyst reactivity and stability and the carboxylate derived from 4 could be easily recovered and reused for several cycles under the mild reaction conditions. © 2009 The Royal Society of Chemistry.
Açıklama
Anahtar Kelimeler
Kaynak
Journal of the Chemical Society. Dalton Transactions
WoS Q Değeri
Scopus Q Değeri
Q1
Cilt
Sayı
35
