Preparation and characterization of sodium dodecyl sulfate doped polypyrrole solid phase micro extraction fiber and its application to endocrine disruptor pesticide analysis

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dc.contributor.authorKorba, Korcan
dc.contributor.authorPelit, Levent
dc.contributor.authorPelit, Fusun Okcu
dc.contributor.authorOzdokur, K. Volkan
dc.contributor.authorErtas, Hasan
dc.contributor.authorEroglu, Ahmet E.
dc.contributor.authorErtas, F. Nil
dc.date.accessioned2019-10-27T21:51:59Z
dc.date.available2019-10-27T21:51:59Z
dc.date.issued2013
dc.departmentEge Üniversitesien_US
dc.description.abstractA robust in house solid-phase micro extraction (SPME) surface has been developed for the headspace (HS)-SPME determination of endocrine disruptor pesticides, namely, Chlorpyrifos, Penconazole, Procymidone, Bromopropylate and Lambda-Cyhalothrin in wine sample by using sodium dodecylsulfate doped polypyrrole SPME fiber. Pyrrole monomer was electrochemically polymerized on a stainless steel wire in laboratory conditions in virtue of diminishing the cost and enhancing the analyte retention on its surface to exert better selectivity and hence the developed polymerized surface could offer to analyst to exploit it as a fiber in headspace SPME analysis. The parameters, mainly, adsorption temperature and time, desorption temperature, stirring rate and salt amount were optimized to be as 70 degrees C and 45 min, 200 degrees C, 600 rpm and 10 g L-1, respectively. Limit of detection was estimated in the range of 0.073-1.659 ng mL(-1) for the pesticides studied. The developed method was applied in to red wine sample with acceptable recovery values (92-107%) which were obtained for these selected pesticides. (C) 2013 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipEge UniversityEge University [2010/Fen/033]en_US
dc.description.sponsorshipThe authors thank to the Ege University for financial support (Project 2010/Fen/033).en_US
dc.identifier.doi10.1016/j.jchromb.2013.04.023en_US
dc.identifier.endpage96en_US
dc.identifier.issn1570-0232
dc.identifier.issn1873-376X
dc.identifier.pmid23669608en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage90en_US
dc.identifier.urihttps://doi.org/10.1016/j.jchromb.2013.04.023
dc.identifier.urihttps://hdl.handle.net/11454/47428
dc.identifier.volume929en_US
dc.identifier.wosWOS:000320085300015en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Chromatography B-Analytical Technologies in the Biomedical and Life Sciencesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPolypyrrole fiberen_US
dc.subjectHead space solid phase micro extractionen_US
dc.subjectEndocrine disruptor pesticideen_US
dc.subjectGas chromatographyen_US
dc.subjectRed wineen_US
dc.titlePreparation and characterization of sodium dodecyl sulfate doped polypyrrole solid phase micro extraction fiber and its application to endocrine disruptor pesticide analysisen_US
dc.typeArticleen_US

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