Hydrogen recovery from methylcyclohexane as a chemical hydrogen carrier using a palladium membrane reactor

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dc.contributor.authorYolcular, S.
dc.date.accessioned2019-10-27T22:57:59Z
dc.date.available2019-10-27T22:57:59Z
dc.date.issued2016
dc.departmentEge Üniversitesien_US
dc.description.abstractA Pd membrane has been prepared by electroless plating on the surface of a porous TiO2 tube in this work. The mean thickness of the resulting Pd membrane on the modified tube was 13 mu m. The hydrogen permeation flux was as high as 0.16 mol m(-2) s(-1) with a pressure difference of 108.75 Pa at 648 K. H-2 permeances were 1.6 x 10(-7)-6.4 x 10(-7)/molm(-2) s(-1) Pa-1/at 580-650 K. The separation factor of H-2/N-2 was over 1,000. Measurements of the temperature coefficient for hydrogen permeation through the membrane gave a value of 9.49 kJ mol(-1) in good agreement with previous reports. The results showed that the prepared membranes can be used in membrane reactors for H-2 permeation in the dehydrogenation of methylcyclohexane.en_US
dc.identifier.doi10.1080/15567036.2015.1030476
dc.identifier.endpage2152en_US
dc.identifier.issn1556-7036
dc.identifier.issn1556-7230
dc.identifier.issn1556-7036en_US
dc.identifier.issn1556-7230en_US
dc.identifier.issue14en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2148en_US
dc.identifier.urihttps://doi.org/10.1080/15567036.2015.1030476
dc.identifier.urihttps://hdl.handle.net/11454/51398
dc.identifier.volume38en_US
dc.identifier.wosWOS:000382363800023en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofEnergy Sources Part A-Recovery Utilization and Environmental Effectsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectElectroless platingen_US
dc.subjecthydrogen separationen_US
dc.subjectPd membraneen_US
dc.subjectPden_US
dc.subjectTiO2 membraneen_US
dc.titleHydrogen recovery from methylcyclohexane as a chemical hydrogen carrier using a palladium membrane reactoren_US
dc.typeArticleen_US

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