Photopolymerization and characterization of vinyl imidazole based allyl derivative polymers; Cr3+ and Cd2+ metal adsorption and antibacterial studies

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dc.authoridMURAT SALTAN, Gozde/0000-0002-9097-3716
dc.contributor.authorSaltan, Fehmi
dc.contributor.authorSaltan, Goezde Murat
dc.contributor.authorIlktac, Raif
dc.contributor.authorOzdokur, Kemal Volkan
dc.date.accessioned2024-08-31T07:46:53Z
dc.date.available2024-08-31T07:46:53Z
dc.date.issued2024
dc.departmentEge Üniversitesien_US
dc.description.abstractA new type polymeric adsorbent, poly(allylphenol-co-hydroxyethyl methacrylate-co-vinyl imidazole) (PAHV), is synthesized in this study. 2-Hydroxyethyl methacrylate is used as complementary monomers along with 1-vinyl imidazole and allylphenol monomers. The photopolymerization method is preferred as a synthesis method and benzophenone is used as the photoinitiator. The effectiveness of the PAHV against bacterial species such as Escherichia coli and Staphylococcus aureus is investigated by the Clinical and Laboratory Standards Institute (CLSI) disk diffusion method. The inhibition areas of PA(1)H(1)V(3) and PA(1)H(1)V(1) derivatives against E. coli and S. aureus are measured as 25 mm +/- 0.25 mm and 7 mm +/- 0.1 mm; 20 mm +/- 0.25 mm, and 5 mm +/- 0.1 mm, respectively. Sorption efficiencies (%) at pH = 6 (selected optimum pH) for 100 mu g/L Cd and Cr of the PA(1)H(1)V(1), PA(1)H(3)V(1), and PA(1)H(1)V(3) derivatives are found to be 69.0 +/- 2.7 and 58.3 +/- 6.7, 66.8 +/- 6.2 and 75.8 +/- 5.5, and 97.2 +/- 3.7 and 97.7 +/- 3.2 (n = 3), respectively. Adsorption studies revealed that the PA1H1V3 polymer can be used as an alternative for the sorption of cadmium and chromium. The pseudo-second-order model and Langmuir isotherm model fits for both adsorption processes. The adsorption capacities obtained from the Langmuir isotherm model for chromium and cadmium sorption are 52.63 and 68.49 mu g g(-1), respectively.en_US
dc.description.sponsorshipResearch Council of Manisa Celal Bayar University [2021-110]en_US
dc.description.sponsorshipThis work was supported by the Research Council of Manisa Celal Bayar University with the project number of 2021-110.en_US
dc.identifier.doi10.1002/app.55756
dc.identifier.issn0021-8995
dc.identifier.issn1097-4628
dc.identifier.issue32en_US
dc.identifier.scopus2-s2.0-85194408406en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/app.55756
dc.identifier.urihttps://hdl.handle.net/11454/104222
dc.identifier.volume141en_US
dc.identifier.wosWOS:001230407000001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240831_Uen_US
dc.subjectAdsorptionen_US
dc.subjectApplicationsen_US
dc.subjectCopolymersen_US
dc.subjectPhotopolymerizationen_US
dc.subjectSynthesis And Processing Techniquesen_US
dc.titlePhotopolymerization and characterization of vinyl imidazole based allyl derivative polymers; Cr3+ and Cd2+ metal adsorption and antibacterial studiesen_US
dc.typeArticleen_US

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