Transfer Hydrogenation of Ketones by Ruthenium Complexes Bearing Benzimidazol-2-ylidene Ligands
Küçük Resim Yok
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-Blackwell
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A series of benzimidazolium ligand precursors were metalated with [RuCl(2)(p-cymene)](2) to give ruthenium(II) N-heterocyclic carbene complexes. All compounds were fully characterized by elemental analyses, (1)H NMR, (13)C NMR, and IR spectroscopy. The new benzimidazol-2-ylidene complexes have been found to be effective catalysis for the transfer hydrogenation of ketones by using 2-propanol as the hydrogen source in the presence of KOH.
Açıklama
Anahtar Kelimeler
Nitrogen heterocycles, Carbene ligands, Ruthenium, Hydrogenation, Ketones
Kaynak
European Journal of Inorganic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
Sayı
19