Transfer Hydrogenation of Ketones by Ruthenium Complexes Bearing Benzimidazol-2-ylidene Ligands

Küçük Resim Yok

Tarih

2010

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Wiley-Blackwell

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

A series of benzimidazolium ligand precursors were metalated with [RuCl(2)(p-cymene)](2) to give ruthenium(II) N-heterocyclic carbene complexes. All compounds were fully characterized by elemental analyses, (1)H NMR, (13)C NMR, and IR spectroscopy. The new benzimidazol-2-ylidene complexes have been found to be effective catalysis for the transfer hydrogenation of ketones by using 2-propanol as the hydrogen source in the presence of KOH.

Açıklama

Anahtar Kelimeler

Nitrogen heterocycles, Carbene ligands, Ruthenium, Hydrogenation, Ketones

Kaynak

European Journal of Inorganic Chemistry

WoS Q Değeri

Q2

Scopus Q Değeri

Q2

Cilt

Sayı

19

Künye