Low-pressure catalytic wet air oxidation of aniline over Co 3O4/CeO21

dc.contributor.authorErsöz G.
dc.contributor.authorAtalay S.
dc.date.accessioned2019-10-26T22:43:17Z
dc.date.available2019-10-26T22:43:17Z
dc.date.issued2010
dc.departmentEge Üniversitesien_US
dc.description.abstractLow-pressure catalytic wet air oxidation of aniline was investigated in a bubble reactor over Co3O4 (10% wt)/CeO2. The catalyst was prepared by sol-gel technology and characterized by using scanning electron microscope, X-ray diffraction, nitrogen adsorption, and thermogravimetric analysis techniques. The aim was to search for the conditions to destroy the aniline content by avoiding production of byproducts such as ammonium, nitrate, and nitrite ions. The reaction was optimized at 0.5 g/L catalyst loading at 150 d`C with a pressure of 4 atm, in 2 h with an air flow rate of 1.36 L/min. A 35.15% amount of aniline was removed, and 14% of the input nitrogen was converted into N2 gas. To evaluate the stability of the catalyst, two consecutive runs were performed by reusing the catalyst recovered. The highest removal with the reused catalyst was found as 34.94%, showing that Co3O4/CeO2 is a stable catalyst. © 2010 American Chemical Society.en_US
dc.identifier.doi10.1021/ie901383e
dc.identifier.endpage1630en_US
dc.identifier.issn0888-5885
dc.identifier.issn0888-5885en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1625en_US
dc.identifier.urihttps://doi.org/10.1021/ie901383e
dc.identifier.urihttps://hdl.handle.net/11454/20021
dc.identifier.volume49en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofIndustrial and Engineering Chemistry Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titleLow-pressure catalytic wet air oxidation of aniline over Co 3O4/CeO21en_US
dc.typeArticleen_US

Dosyalar