Magnetic dispersive micro solid phase extraction method by Fe3O4/Ni/NixB magnetic nanoparticles for determination of endocrine disruptor pesticides

Basit Öğe Kaydı
dc.authorscopusid57374146700
dc.authorscopusid58087367900
dc.authorscopusid43461640900
dc.contributor.authorErbaş, İ.
dc.contributor.authorDeniz, Çiftçi, T.
dc.contributor.authorPelit, F.
dc.date.accessioned2024-08-25T18:31:55Z
dc.date.available2024-08-25T18:31:55Z
dc.date.issued2023
dc.departmentEge Üniversitesien_US
dc.description.abstractIn this this work, magnetic adsorbent Fe3O4/Ni/NixB nanocomposite was synthesized and used first time for the extraction of pesticides. A magnetic dispersive micro solid phase extraction (MD-µ-SPE) procedure was developed using this nanocomposite. The synthesized magnetic nanoparticles were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), transmission electron microscope (TEM), Brunauer-Emmett-Teller (BET) measurements was also done for taking information on the nanocomposite material's surface area, pore size, and adsorption properties. Statistical the parameters related to the extraction efficiency were screened by statistical experimental design methods including Plackett Burmann and Box-Behnken for optimization purposes. The extraction performance of Lambda-Cyhalothrin (LMD) and Bromopropylate (BRP) pesticides in well water samples was tested using gas chromatography with an electron capture detector (GC-ECD). Under the optimized conditions, linear calibration plots were obtained by the regression coefficients (>0.99), and the linear range was found to be between 0.1 and 5 ng mL?1. The detection limits and recovery values for LMD and BRP were calculated as 0.03–0.02 ng mL?1 and 90–89% respectively. The enrichment factors were calculated as 30.3 for BRP and 393 for LMD. This work shows the potential of the magnetic adsorbent Fe3O4/Ni/NixB nanocomposite as an alternative sorbent for the MD-µ-SPE extraction procedure. © 2023 Elsevier B.V.en_US
dc.description.sponsorshipEge Üniversitesi: 2017/FEN/069en_US
dc.description.sponsorshipThe authors thank to the Ege University (2017/FEN/069) for financial support. We are grateful to Ege University Planning and Monitoring Coordination of Organizational Development and Directorate of Library and Documentation for their support in editing and proofreading service of this study. Also the authors also thank to Gökçe TANIYAN for preparing images of the manuscript.en_US
dc.identifier.doi10.1016/j.microc.2023.108909
dc.identifier.issn0026-265X
dc.identifier.scopus2-s2.0-85160778396en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.microc.2023.108909
dc.identifier.urihttps://hdl.handle.net/11454/100073
dc.identifier.volume191en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Inc.en_US
dc.relation.ispartofMicrochemical Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.snmz20240825_Gen_US
dc.subjectExperimental designen_US
dc.subjectFe3O4/Ni/NixB adsorbenten_US
dc.subjectGas Chromatographyen_US
dc.subjectGreen chemistryen_US
dc.subjectMagnetic dispersive micro solid phase extraction (MD-µ-SPE)en_US
dc.subjectPesticidesen_US
dc.titleMagnetic dispersive micro solid phase extraction method by Fe3O4/Ni/NixB magnetic nanoparticles for determination of endocrine disruptor pesticidesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

Scopus İndeksli Yayınlar Koleksiyonu