Synthesis, structural characterization, oxygen sensitivity, and antimicrobial activity of ruthenium(II) carbonyl complexes with thiosemicarbazones

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dc.contributor.authorOzturk, Nurdan
dc.contributor.authorYaman, Pelin Kose
dc.contributor.authorYavuz, Murat
dc.contributor.authorOter, Ozlem
dc.contributor.authorTimur, Suna
dc.contributor.authorSubasi, Elif
dc.date.accessioned2019-10-27T22:05:43Z
dc.date.available2019-10-27T22:05:43Z
dc.date.issued2014
dc.departmentEge Üniversitesien_US
dc.description.abstractRu(II) carbonyl complexes were prepared by reacting [Ru(H)(Cl)(CO)(PPh3)(3)] with the respective thiosemicarbazone ligands and the complexes were characterized by UV-vis, FT-IR, and H-1 and P-31 NMR spectroscopy. Oxygen sensitivities and antimicrobial activities of the complexes were determined. [Ru(CO)(PPh3)(2)(eta(3)-O, N-3, S-TSC1)] (1), [Ru(Cl)(CO)(PPh3)(2)(eta(2)-N-3, S-TSC2)] (2), and [Ru(Cl)(CO) (PPh3)2(eta(2)-N-3,S-TSC3)] (3) have been prepared by reacting [Ru(H)(Cl)(CO)(PPh3)(3)] with the respective thiosemicarbazones TSC1 (2-hydroxy-3-methoxybenzaldehyde thiosemicarbazone), TSC2 (3-hydroxybenzaldehyde thiosemicarbazone), and TSC3 (3,4-dihydroxybenzaldehyde thiosemicarbazone) in a 1 : 1 M ratio in toluene and all of the complexes have been characterized by UV-vis, FT-IR, and H-1 and P-31 NMR spectroscopy. The spectroscopic studies showed that TSC1 is coordinated to the central metal as a tridendate ligand coordinating via the azomethine nitrogen (C=N), phenolic oxygen, and sulfur to ruthenium in 1, whereas TSC2 and TSC3 are coordinated to ruthenium as a bidentate ligand through azomethine nitrogen (C=N) and sulfur in 2 and 3. Oxygen sensitivities of 1-3 and [Ru(Cl)(CO)(PPh3)(2)(eta(2)-N-3, S-TSC4)] (4), and antimicrobial activities of 1-3 have been determined.en_US
dc.description.sponsorshipDokuz Eylul University Rectorship, Scientific Research Project Coordination CenterDokuz Eylul University [2011.KB. FEN.047, 2012.KB. FEN.047]en_US
dc.description.sponsorshipThis study was supported by project number 2011.KB. FEN.047 and 2012.KB. FEN.047 from Dokuz Eylul University Rectorship, Scientific Research Project Coordination Center. We also thank the Graduate School of Natural and Applied Sciences, Dokuz Eylul University, EBILTEM, Ege University for NMR analysis, and TUBITAK, for elemental analysis.en_US
dc.identifier.doi10.1080/00958972.2014.948433
dc.identifier.endpage2700en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issn0095-8972en_US
dc.identifier.issn1029-0389en_US
dc.identifier.issue16en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage2688en_US
dc.identifier.urihttps://doi.org/10.1080/00958972.2014.948433
dc.identifier.urihttps://hdl.handle.net/11454/48569
dc.identifier.volume67en_US
dc.identifier.wosWOS:000342306700003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRuthenium(II) carbonyl complexesen_US
dc.subjectThiosemicarbazonesen_US
dc.subjectOxygen sensitivityen_US
dc.subjectAntimicrobial activitiesen_US
dc.titleSynthesis, structural characterization, oxygen sensitivity, and antimicrobial activity of ruthenium(II) carbonyl complexes with thiosemicarbazonesen_US
dc.typeArticleen_US

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