Adsorptive Cathodic Stripping Voltammetric Determination of Boscalid in the Presence of Cobalt Ions at a Pencil Lead Electrode

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dc.contributor.authorAydin, Irem
dc.contributor.authorPelit, Levent
dc.contributor.authorErtas, F. Nil
dc.date.accessioned2019-10-27T10:47:03Z
dc.date.available2019-10-27T10:47:03Z
dc.date.issued2018
dc.departmentEge Üniversitesien_US
dc.description.abstractHere is described a novel voltammetric method for boscalid. Boscalid is a broad-spectrum fungicide known to be electrochemically inactive. However, it forms complexes with cobalt(II) through its pyridine carboxamide group that allows its indirect determination by adsorptive cathodic stripping voltammetry after deposition at positive potentials. The catalytic character of the reduction peak at -1.2 V was established by the mechanistic studies. After optimization of the parameters, calibration relationships were obtained at nanomolar concentrations and the method was used to analyze tomato juice and tomato paste with satisfactory recoveries.en_US
dc.description.sponsorshipTurkish Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [114Z394]; Ege University Research Fund projects [2015 FEN 033]en_US
dc.description.sponsorshipThe authors would like to thank the Turkish Scientific and Technological Research Council of Turkey (TUBITAK) (Project no: 114Z394) and Ege University Research Fund projects (2015 FEN 033).en_US
dc.identifier.doi10.1080/00032719.2017.1312424
dc.identifier.endpage220en_US
dc.identifier.issn0003-2719
dc.identifier.issn1532-236X
dc.identifier.issn0003-2719en_US
dc.identifier.issn1532-236Xen_US
dc.identifier.issue01.Feben_US
dc.identifier.startpage209en_US
dc.identifier.urihttps://doi.org/10.1080/00032719.2017.1312424
dc.identifier.urihttps://hdl.handle.net/11454/31375
dc.identifier.volume51en_US
dc.identifier.wosWOS:000416519900016en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofAnalytical Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAdsorptive cathodic stripping voltammetry (AdCSV)en_US
dc.subjectboscaliden_US
dc.subjectcatalytic reactionen_US
dc.subjectpencil lead electrode (PLE)en_US
dc.subjecttomato juiceen_US
dc.subjecttomato pasteen_US
dc.titleAdsorptive Cathodic Stripping Voltammetric Determination of Boscalid in the Presence of Cobalt Ions at a Pencil Lead Electrodeen_US
dc.typeArticleen_US

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