A highly novel dinickel complex: A hydrogen-bonded anti-skew carboxylate bridge and a 2D supramolecular structure

dc.contributor.authorKorkmaz, Neslihan
dc.contributor.authorGokce, Aytac Gurhan
dc.contributor.authorAstley, Stephen T.
dc.contributor.authorAygun, Muhittin
dc.contributor.authorAstley, Demet
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2019-10-27T21:19:11Z
dc.date.available2019-10-27T21:19:11Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractReaction of the tridentate Schiff base ligands obtained from 2,4-dihydroxybenzaldehyde and either L-iso-leucine or L-tert-leucine with Ni(NO3)(2) in methanol/water solution in the presence of base afforded dinickel complexes. The crystal structure of the product derived from L-tert-leucine has been determined by X-ray crystallography. The octahedrally coordinated two Ni centers were found to be bridged by a single carboxylate group in an extremely unusual non-planar fashion. A 2D supramolecular structure, constructed by infinite hydrogen-bonded complex sheets parallel to the ab-plane of the unit cell, arises from intermolecular O-H center dot center dot center dot O hydrogen bonds. (C) 2009 Elsevier B.V. All rightsen_US
dc.description.sponsorshipEge University Faculty of ScienceEge University; TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [107T778]en_US
dc.description.sponsorshipThe authors are grateful to Ege University Faculty of Science and to TUBITAK (Grant 107T778) for financial support of this work. The authors also acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased under Grant No. F.279 of the University Research Fund).en_US
dc.identifier.doi10.1016/j.inoche.2009.09.021
dc.identifier.endpage1208en_US
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.issn1387-7003en_US
dc.identifier.issn1879-0259en_US
dc.identifier.issue12en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1204en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2009.09.021
dc.identifier.urihttps://hdl.handle.net/11454/44109
dc.identifier.volume12en_US
dc.identifier.wosWOS:000272570500010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectDinickel complexesen_US
dc.subjectBridging carboxylateen_US
dc.subjectSupramolecular structureen_US
dc.subjectTridentate Schiff baseen_US
dc.titleA highly novel dinickel complex: A hydrogen-bonded anti-skew carboxylate bridge and a 2D supramolecular structureen_US
dc.typeArticleen_US

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