A highly novel dinickel complex: A hydrogen-bonded anti-skew carboxylate bridge and a 2D supramolecular structure
dc.contributor.author | Korkmaz, Neslihan | |
dc.contributor.author | Gokce, Aytac Gurhan | |
dc.contributor.author | Astley, Stephen T. | |
dc.contributor.author | Aygun, Muhittin | |
dc.contributor.author | Astley, Demet | |
dc.contributor.author | Buyukgungor, Orhan | |
dc.date.accessioned | 2019-10-27T21:19:11Z | |
dc.date.available | 2019-10-27T21:19:11Z | |
dc.date.issued | 2009 | |
dc.department | Ege Üniversitesi | en_US |
dc.description.abstract | Reaction of the tridentate Schiff base ligands obtained from 2,4-dihydroxybenzaldehyde and either L-iso-leucine or L-tert-leucine with Ni(NO3)(2) in methanol/water solution in the presence of base afforded dinickel complexes. The crystal structure of the product derived from L-tert-leucine has been determined by X-ray crystallography. The octahedrally coordinated two Ni centers were found to be bridged by a single carboxylate group in an extremely unusual non-planar fashion. A 2D supramolecular structure, constructed by infinite hydrogen-bonded complex sheets parallel to the ab-plane of the unit cell, arises from intermolecular O-H center dot center dot center dot O hydrogen bonds. (C) 2009 Elsevier B.V. All rights | en_US |
dc.description.sponsorship | Ege University Faculty of ScienceEge University; TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [107T778] | en_US |
dc.description.sponsorship | The authors are grateful to Ege University Faculty of Science and to TUBITAK (Grant 107T778) for financial support of this work. The authors also acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased under Grant No. F.279 of the University Research Fund). | en_US |
dc.identifier.doi | 10.1016/j.inoche.2009.09.021 | |
dc.identifier.endpage | 1208 | en_US |
dc.identifier.issn | 1387-7003 | |
dc.identifier.issn | 1879-0259 | |
dc.identifier.issn | 1387-7003 | en_US |
dc.identifier.issn | 1879-0259 | en_US |
dc.identifier.issue | 12 | en_US |
dc.identifier.scopusquality | N/A | en_US |
dc.identifier.startpage | 1204 | en_US |
dc.identifier.uri | https://doi.org/10.1016/j.inoche.2009.09.021 | |
dc.identifier.uri | https://hdl.handle.net/11454/44109 | |
dc.identifier.volume | 12 | en_US |
dc.identifier.wos | WOS:000272570500010 | en_US |
dc.identifier.wosquality | Q2 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Elsevier Science Bv | en_US |
dc.relation.ispartof | Inorganic Chemistry Communications | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Dinickel complexes | en_US |
dc.subject | Bridging carboxylate | en_US |
dc.subject | Supramolecular structure | en_US |
dc.subject | Tridentate Schiff base | en_US |
dc.title | A highly novel dinickel complex: A hydrogen-bonded anti-skew carboxylate bridge and a 2D supramolecular structure | en_US |
dc.type | Article | en_US |