Dichlorido[1-(2-methyl-benz-yl)-3-(?6-2,4, 6-trimethyl-benz-yl)-1H-2,3-dihydro-benzimidazol-2-yl-idene]ruthenium(II) dichloro-methane solvate

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dc.contributor.authorArslan H.
dc.contributor.authorVanderveer D.
dc.contributor.authorYaar S.
dc.contributor.authorZdemir I.
dc.contributor.authorEtinkaya B.
dc.date.accessioned2019-10-27T08:35:55Z
dc.date.available2019-10-27T08:35:55Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractThe title complex, [RuClCl]·CHl is best thought of as containing an octa-hedrally coordinated Ru center with the arene occupying three sites. Two Ru - Cl bonds and one Ru-carbene bond complete the distorted octa-hedron. The carbene portion of the ligand is a benzimidazole ring. This ring is connected to the CCHarene group by a CHbridge. This leads to a system with very little apparent strain. A dichloro-methane solvent mol-ecule completes the crystal structure. Further stabilization is accomplished via C - H?N and C - H?Cl interactions.en_US
dc.identifier.doi10.1107/S160053680900350X
dc.identifier.endpagem244en_US
dc.identifier.issn1600-5368
dc.identifier.issn1600-5368en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpagem243en_US
dc.identifier.urihttps://doi.org/10.1107/S160053680900350X
dc.identifier.urihttps://hdl.handle.net/11454/27314
dc.identifier.volume65en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofActa Crystallographica Section E: Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleDichlorido[1-(2-methyl-benz-yl)-3-(?6-2,4, 6-trimethyl-benz-yl)-1H-2,3-dihydro-benzimidazol-2-yl-idene]ruthenium(II) dichloro-methane solvateen_US
dc.typeArticleen_US

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