Photosynthesis of rose oxide by concentrated sunlight in the absence of singlet oxygen

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dc.contributor.authorDincalp, H
dc.contributor.authorIcli, S
dc.date.accessioned2019-10-27T18:19:51Z
dc.date.available2019-10-27T18:19:51Z
dc.date.issued2001
dc.departmentEge Üniversitesien_US
dc.description.abstractRose oxide was photosynthesized in aerated acetonitrile solutions from citronellol via aromatic diimide (dehydroabietyl perylene diimide and n-butyl naphthalene diimide (BUNAP)) singlet photosensitizers under sodium light (0.2-0.4 sun) and concentrated sun light (90-100 sun). The yield of formation of rose oxide is high by concentrated sun light, with respect to sodium light irradiation. It was shown that, (I) super oxide anion radical results in the production of rose oxide from citronellol as seen previously with singlet oxygen; (II) photo-and thermal-stable aromatic diimides are capable of producing rose oxide in high yield by 100-fold concentrated sun light conditions. The addition of cupric and ferric ions to acetonitrile solutions lowered the yield of rose oxide formation. (C) 2001 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S1010-6030(01)00457-9
dc.identifier.endpage151en_US
dc.identifier.issn1010-6030
dc.identifier.issn1010-6030en_US
dc.identifier.issue02.Maren_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage147en_US
dc.identifier.urihttps://doi.org/10.1016/S1010-6030(01)00457-9
dc.identifier.urihttps://hdl.handle.net/11454/35731
dc.identifier.volume141en_US
dc.identifier.wosWOS:000169668100008en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Photochemistry and Photobiology A-Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectsuper oxide anion radicalen_US
dc.subjectperylene diimideen_US
dc.subjectnaphthalene diimideen_US
dc.subjectsolar concentratoren_US
dc.titlePhotosynthesis of rose oxide by concentrated sunlight in the absence of singlet oxygenen_US
dc.typeArticleen_US

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