Thermal reactions of dimanganese decacarbonyl with tetraalkyldiphosphine disulfides (R = Me, Et, Prn, Bun) and crystal structure of [Mn2(CO)8 (µ-PBu2n)2]
Küçük Resim Yok
Tarih
2002
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Reaction of Mn2(CO)10 with R2P(S)P(S)R2 (R = Me, Et, Prn, Bun) in toluene at 120°C yields binuclear [Mn2(CO)8(µ-PR2)2] and trinuclear [Mn(CO)3(µ-S=PR2)]3 complexes. Both result from phosphorus-phosphorus bond scission, while in the former sulfur abstraction has also occurred. An X-ray diffraction study of [Mn2(CO)8 (µ-PBu2n)2] confirms that the manganese adopts a distorted octahedral geometry with local C2v symmetry. © 2002 Elsevier Science Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Dimanganese decacarbonyl, Diphosphine disulfide, Phosphido, Phosphidosulfide
Kaynak
Polyhedron
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
21
Sayı
7
