Direct conversion of biomass to platform chemicals, catalyzed using a deep eutectic solvent of N,N diethyl ethanol ammonium chloride-oxalic acid in a microwave reactor

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dc.contributor.authorArslanoglu, Alpaslan
dc.contributor.authorSert, Murat
dc.date.accessioned2019-10-27T09:40:53Z
dc.date.available2019-10-27T09:40:53Z
dc.date.issued2019
dc.departmentEge Üniversitesien_US
dc.description.abstractNowadays, the production of platform chemicals from cellulose is found as promising way to obtain valuable products from renewable sources instead of fossil fuel sources. In this study, conversion of cellulose into valuable products by using deep eutectic solvent as catalyst has been studied. The performance of deep eutectic solvent formed by N,N diethylethanol ammonium chloride and oxalic acid was evaluated for the conversion of cellulose in the microwave reactor. Deep eutectic solvent can be easily formed by mixing hydrogen bond acceptor and hydrogen bond donor at specified ratio. Deep eutectic solvents are found promising for processing of biomass and also to obtain ecofriendly systems due to the green nature of deep eutectic solvents (DES). This study show the applicability of DES formed by N,N diethyl ethanol ammonium chloride and oxalic acid in the conversion of cellulose at a temperature of 150, 160 and 170 degrees C and 2.5, 5.0 and 7.5 reaction time. The maximum C efficiency was achieved as 38.4% at 170 degrees C and 5 min reaction time in microwave reactor.en_US
dc.description.sponsorshipEge University-EbiltemEge University [2015 BIL 020]; TUBITAKTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [214M001]en_US
dc.description.sponsorshipThis study was supported by Ege University-Ebiltem (Grant No. 2015 BIL 020) and TUBITAK (Project: 214M001) research projects.en_US
dc.identifier.doi10.1016/j.fuel.2019.116142
dc.identifier.issn0016-2361
dc.identifier.issn1873-7153
dc.identifier.issn0016-2361en_US
dc.identifier.issn1873-7153en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.fuel.2019.116142
dc.identifier.urihttps://hdl.handle.net/11454/28549
dc.identifier.volume258en_US
dc.identifier.wosWOS:000487820500052en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofFuelen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBiomassen_US
dc.subjectLevulinic aciden_US
dc.subject5-Hydroxymethyl furfuralen_US
dc.subjectDeep eutectic solventsen_US
dc.subjectMicrowave reactoren_US
dc.titleDirect conversion of biomass to platform chemicals, catalyzed using a deep eutectic solvent of N,N diethyl ethanol ammonium chloride-oxalic acid in a microwave reactoren_US
dc.typeArticleen_US

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