Photochemical complexation reactions of M(CO)6 (M=Cr, Mo, W) and Re(CO)5Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodanines

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dc.contributor.authorSubasi E.
dc.contributor.authorErcag A.
dc.contributor.authorSert S.
dc.contributor.authorSenturk O.S.
dc.date.accessioned2019-10-27T08:58:58Z
dc.date.available2019-10-27T08:58:58Z
dc.date.issued2006
dc.departmentEge Üniversitesien_US
dc.description.abstractThe new complexes [M(CO)5-DABRd] [M=Cr; 1, Mo; 2, W; 3], [cis-Re(CO)4Br-DABRd] (4), [M(CO)5-BRd] [M=Cr; 5, Mo; 6, W; 7] and [Mo(CO)5-L] [L=Rd, 8; 2CBRd, 9; 2HNARd, 10; IBRd, 11] have been synthesized by the photochemical reactions of VIB and VIIB group metal carbonyls [M(CO)6] [M=Cr, Mo, W] and [Re(CO)5Br] with 5-(4-dimethylaminobenzylidene)rhodanine (DABRd), 5-benzylidenerhodanine (BRd), rhodanine (Rd), 5-(2-chlorobenzylidene)rhodanine (2CBRd), 5-(2- hydroxynaphtylidene)rhodanine (2HNARd), 5-(4-isopropylbenzylidene)rhodanine (IBRd) and characterized by elemental analysis, FT-IR, 1H and 13C-{1H}-NMR spectroscopy and by Mass spectrometry. The spectroscopic studies show that all rhodanine ligands act as monodentate ligands coordinating via the sulfur (CS) donor atom in (1-11).en_US
dc.description.sponsorshipIstanbul Üniversitesi: 818/190496en_US
dc.description.sponsorshipWe thank BP (Turkey) for the provision of photochemical apparatus and Research Foundation of Ege and Dokuz Eylul University for funds. We thank TUBITAK for allocation of time at the Mass Spectra and Elemental Analyses. We thank Dr. Yurdanur Yayla for obtaining 1Hand 13C-f1Hg-NMR. spectra at Ege University. This work also supported by Research Fund of Istanbul University, Project Number: 818/190496, and Dokuz Eylul University, Project Number: 04.KB.FEN.106. --en_US
dc.identifier.doi10.1080/15533170601028116
dc.identifier.endpage711en_US
dc.identifier.issn1553-3174
dc.identifier.issn1553-3174en_US
dc.identifier.issue10en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage705en_US
dc.identifier.urihttps://doi.org/10.1080/15533170601028116
dc.identifier.urihttps://hdl.handle.net/11454/27622
dc.identifier.volume36en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject5-benzylidenerhodaninesen_US
dc.subjectMetal carbonyl complexesen_US
dc.subjectOrganometallic compoundsen_US
dc.subjectRhodanine (4-thiazolidinone-2-thioxo)en_US
dc.titlePhotochemical complexation reactions of M(CO)6 (M=Cr, Mo, W) and Re(CO)5Br with rhodanine (4-thiazolidinone-2-thioxo) and 5-substituted rhodaninesen_US
dc.typeArticleen_US

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