Synthesis of an amphiphilic ruthenium complex with swallow-tail bipyridyl ligand and its application in nc-DSC

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dc.contributor.authorSahin, Cigdem
dc.contributor.authorTozlu, Cem
dc.contributor.authorOcakoglu, Kasim
dc.contributor.authorZafer, Ceylan
dc.contributor.authorVarlikli, Canan
dc.contributor.authorIcli, Siddik
dc.date.accessioned2019-10-27T19:55:19Z
dc.date.available2019-10-27T19:55:19Z
dc.date.issued2008
dc.departmentEge Üniversitesien_US
dc.description.abstractAn amphiphilic swallow-tail bipyridyl ligand, 4,4'-bis(dihexylmethyl)-2,2'-bipyridine, and its heteroleptic ruthenium (II) complex were synthesized starting from dichloro-(p-cymene) ruthenium (II) dimer. The complex was characterized by UV/Vis and FTIR spectro-photometers, NMR spectroscopy and cyclic voltammetry. The performance of this complex as charge transfer photosensitizer in nc-TiO2 based dye sensitized solar cells was studied under standard AM 1.5 sunlight and by using an electrolyte consisting of 0.6 M N-methyl-N-butyl imidazolium iodide (BMII), 0.1 M LiI, 0.05 M I-2, 0.5 M 4-tert-butyl pyridine (TBP) in acetonitrile. The complex, CS9 in DMF, gave a photocurrent density of 12.62 mA/cm(2), 630 mV open circuit potential and 0.62 fill factor yielding 5.68% efficiency. (c) 2007 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.ica.2007.05.022
dc.identifier.endpage676en_US
dc.identifier.issn0020-1693
dc.identifier.issn0020-1693en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage671en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2007.05.022
dc.identifier.urihttps://hdl.handle.net/11454/40665
dc.identifier.volume361en_US
dc.identifier.wosWOS:000254426600013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectamphiphilic ruthenium (II) complexen_US
dc.subjectswallow-tail bipyridyl liganden_US
dc.subjectdye sensitizeden_US
dc.titleSynthesis of an amphiphilic ruthenium complex with swallow-tail bipyridyl ligand and its application in nc-DSCen_US
dc.typeArticleen_US

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