Dithizone, carminic acid and pyrocatechol violet dyes sensitized metal (Ho, Ba& Cd) doped TiO2/CdS nanocomposite as a photoanode in hybrid heterojunction solar cell

dc.authoridUsman, Muhammad/0000-0002-9451-3696
dc.authorscopusid57213508894
dc.authorscopusid36769182600
dc.authorscopusid25624466500
dc.authorscopusid57215720775
dc.authorscopusid57211323464
dc.authorscopusid57210134877
dc.authorscopusid57211929780
dc.authorwosidUsman, Muhammad/R-3183-2018
dc.contributor.authorUllah, Naimat
dc.contributor.authorShah, Syed Mujtaba
dc.contributor.authorErten-Ela, Sule
dc.contributor.authorAnsir, Rotaba
dc.contributor.authorHussain, Hazrat
dc.contributor.authorQamar, Samina
dc.contributor.authorUsman, Muhammad
dc.date.accessioned2023-01-12T19:54:32Z
dc.date.available2023-01-12T19:54:32Z
dc.date.issued2022
dc.departmentN/A/Departmenten_US
dc.description.abstractConsidering the great importance of nanocomposite based photo-active nanomaterials for a variety of elec-tronics, photonics and photovoltaics application, it is always worth considering to synthesize new hetreos-tructure. This paper describes the sol-gel and hydrothermal synthesis of metal (holmium, barium, and cadmium) doped TiO2/CdS nanocomposites for photoanode applications. Various characterization techniques, including XRD, FTIR, UV-VIS, EDX, and SEM were used to examine the synthesized heterostructures. The band gap of pure TiO2 NPs is 3.10 eV, which was effectively decreased to 2.16 eV by doping and coupling with CdS. The nano-material's crystallinity, crystallite size, morphology and elemental composition were determined by XRD, SEM and EDX, respectively. As sensitizers, the organic dyes dithizone, carminic acid, and pyrocatechol violet were used. FTIR was used to analyze the effective dye grafting on the surface of nanomaterials. In the presence of hole conducting P3HT polymer as solid state electrolyte, the sensitized materials were evaluated for solid state dye -sensitized solar cells. Compared to the reference device, Cd-TiO2/CdS photosensitized using Pyrocatechol violet dye demonstrated the highest efficiency of 2.68% (0.82%). Other parameters of this device, including open circuit voltage (Voc) and short circuit current (Jsc), were determined to be 16.97 mA cm2 and 0.41V, respectively.en_US
dc.description.sponsorshipHigher education commission of Pakistan; [6169/Federal/NRPU/R D/HEC/16]en_US
dc.description.sponsorshipWe are greatly appreciative to Higher education commission of Pakistan under project No-6169/Federal/NRPU/R & D/HEC/16 for financial support and Quaid-i-Azam University, Islamabad, for providing laboratory and other facilities.en_US
dc.identifier.doi10.1016/j.ceramint.2022.07.067
dc.identifier.endpage31490en_US
dc.identifier.issn0272-8842
dc.identifier.issn1873-3956
dc.identifier.issn0272-8842en_US
dc.identifier.issn1873-3956en_US
dc.identifier.issue21en_US
dc.identifier.scopus2-s2.0-85135540459en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage31478en_US
dc.identifier.urihttps://doi.org/10.1016/j.ceramint.2022.07.067
dc.identifier.urihttps://hdl.handle.net/11454/76456
dc.identifier.volume48en_US
dc.identifier.wosWOS:000863347400003en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Sci Ltden_US
dc.relation.ispartofCeramics Internationalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCarminic aciden_US
dc.subjectDye sensitized solar cellen_US
dc.subjectHydrothermal methoden_US
dc.subjectDithizoneen_US
dc.subjectPyrocatechol violeten_US
dc.subjectPower conversion efficiencyen_US
dc.subjectPerformanceen_US
dc.subjectCompositesen_US
dc.subjectNanomaterialsen_US
dc.subjectSpectroscopyen_US
dc.subjectHydrogenen_US
dc.titleDithizone, carminic acid and pyrocatechol violet dyes sensitized metal (Ho, Ba& Cd) doped TiO2/CdS nanocomposite as a photoanode in hybrid heterojunction solar cellen_US
dc.typeArticleen_US

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