In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)](2) system for transfer hydrogenation reactions

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dc.contributor.authorOzcan, Emine Ozge
dc.contributor.authorMercan, Deniz
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorCetinkaya, Engin
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2019-10-27T21:25:35Z
dc.date.available2019-10-27T21:25:35Z
dc.date.issued2011
dc.departmentEge Üniversitesien_US
dc.description.abstractHydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3-dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p-cymene)](2) and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.en_US
dc.description.sponsorshipInonu UniversityInonu University [BAP 2011/Gudumlu-4]; Ege UniversityEge University [2006/Fen/066]; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipWe are grateful to Inonu University Research Fund (BAP 2011/Gudumlu-4) and Ege University Research Fund (2006/Fen/066) for their financial support of this work and the Scientific and Technological Research Council of Turkey (TUBITAK) for a grant.en_US
dc.identifier.doi10.3906/kim-1104-4
dc.identifier.endpage709en_US
dc.identifier.issn1300-0527
dc.identifier.issn1300-0527en_US
dc.identifier.issue5en_US
dc.identifier.startpage699en_US
dc.identifier.urihttps://doi.org/10.3906/kim-1104-4
dc.identifier.urihttps://hdl.handle.net/11454/44844
dc.identifier.volume35en_US
dc.identifier.wosWOS:000296049900002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherScientific Technical Research Council Turkey-Tubitaken_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRutheniumen_US
dc.subjecttetrahydropyrimidin-2-ylideneen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjecttransfer hydrogenationen_US
dc.subjectketoneen_US
dc.titleIn situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)](2) system for transfer hydrogenation reactionsen_US
dc.typeArticleen_US

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