A Beneficial Effect of Ortho-Substituents In the Arylation of (Benzene)Tricarbonylmanganese(1+) Hexafluorophosphate(1-)
Küçük Resim Yok
Tarih
1995
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa Lausanne
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
ortho-Substituted aryllithium and aryl Grignard reagents react with (benzene)manganesetricarbonyl cation (1) to give good yields of the expected ring adducts. The presence of the ortho substituent(s) appears to be necessary for the satisfactory outcome of the reaction with aryllithiums. This reactivity opens up the possibility of preparing novel heterocyclic structures via the initial reaction of 1 with functionalised metallated arenes.
Açıklama
Anahtar Kelimeler
MANGANESE, CARBONYL, ARENE COMPLEXES, ORTHOMETALLATION, METAL CARBONYL CATIONS
Kaynak
Journal of Organometallic Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
Cilt
487
Sayı
01.Feb
