A New Donor-Acceptor Double-Cable Carbazole Polymer with Perylene Bisimide Pendant Group: Synthesis, Electrochemical, and Photovoltaic Properties

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dc.contributor.authorKoyuncu, Sermet
dc.contributor.authorZafer, Ceylan
dc.contributor.authorKoyuncu, Fatma Baycan
dc.contributor.authorAydin, Banu
dc.contributor.authorCan, Mustafa
dc.contributor.authorSefer, Emre
dc.contributor.authorOzdemir, Eyup
dc.contributor.authorIcli, Siddik
dc.date.accessioned2019-10-27T20:48:14Z
dc.date.available2019-10-27T20:48:14Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractWe report here electrochemical synthesis of novel soluble donor-acceptor (D-A) polymer with suitably functionalized perylenetetracarboxylic diimide dye derivative covalently linked to carbazole moiety (Cbz-PDI). The band gap, E, was measured using UV-Vis spectroscopy and compared with that obtained by cyclic voltammetry (CV). Efficient intramolecular electron transfer from carbazole-donor to perynediimide-acceptor leads to remarkable fluorescence quenching of the perylene core. Furthermore, spectroelectrochemical property and surface morphology of the polymer film were investigated. Characteristic monoanion and dianion radical bands on the UV-Vis absorption spectra attributed to the electrochemical reduction of the neutral polymer were observed. During the reduction process, red color of the film turned into blue and violet, respectively. Finally, the photovoltaic performance of the D-A double-cable polymer was checked and nearly 0.1% electrical conversion efficiency is obtained under simulated AM 1.5 solar light with 100 mW/cm(2) radiation power. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6280-6291, 2009en_US
dc.description.sponsorshipState Planning Organization of Turkey (DPT); Technical and Scientific Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK)en_US
dc.description.sponsorshipThe authors gratefully acknowledge the supports from the State Planning Organization of Turkey (DPT) and Technical and Scientific Research Council of Turkey (TUBITAK).en_US
dc.identifier.doi10.1002/pola.23671
dc.identifier.endpage6291en_US
dc.identifier.issn0887-624X
dc.identifier.issn0887-624Xen_US
dc.identifier.issue22en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage6280en_US
dc.identifier.urihttps://doi.org/10.1002/pola.23671
dc.identifier.urihttps://hdl.handle.net/11454/42680
dc.identifier.volume47en_US
dc.identifier.wosWOS:000271670000033en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.ispartofJournal of Polymer Science Part A-Polymer Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcarbazoleen_US
dc.subjectconjugated polymersen_US
dc.subjectdonor-acceptor polymersen_US
dc.subjectelectrochemical polymerizationen_US
dc.subjectelectrochemistryen_US
dc.subjectheteroatom-containing polymersen_US
dc.subjectorganic solar cellsen_US
dc.subjectperyleneen_US
dc.titleA New Donor-Acceptor Double-Cable Carbazole Polymer with Perylene Bisimide Pendant Group: Synthesis, Electrochemical, and Photovoltaic Propertiesen_US
dc.typeArticleen_US

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