Diether functionalized rhodium(I)-N-heterocyclic carbene complexes and their catalytic application for transfer hydrogenation reactions

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dc.contributor.authorGulcemal, Suleyman
dc.contributor.authorDaran, Jean-Claude
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T21:25:17Z
dc.date.available2019-10-27T21:25:17Z
dc.date.issued2011
dc.departmentEge Üniversitesien_US
dc.description.abstractN-heterocyclic carbene (NHC) complexes of rhodium(I) (3 and 4) bearing one diether (MeOCH2CH2OCH2-CH2-NHC) functionality on N-1 and bulky benzyl groups (CH2-C6H2(CH3)(3)-2,4,6 and CH2-C-6(CH3)(5)) on N-3 of (5,6-dimethyl)benzimidazole were synthesized by deprotonation of the corresponding benzimidazolium salt with [Rh(mu-OMe)(1,5-cod)](2) in dichloromethane at ambient temperature. All compounds have been fully characterized by elemental analysis, H-1 and C-13 NMR spectroscopy. X-ray diffraction studies on single crystals of 3a and 3b confirm the cis square planar geometry. All of the new benzimidazol-2-ylidene rhodium(I) complexes were found to be effective catalysts for the transfer hydrogenation reaction. (C) 2010 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipEge UniversityEge University [07-FEN-047, 08-BIL-006]; Turkish Academy of Science (TUBA)Turkish Academy of Sciencesen_US
dc.description.sponsorshipFinancial supports from Ege University (Project 07-FEN-047; 08-BIL-006) and The Turkish Academy of Science (TUBA) are gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2010.09.023
dc.identifier.endpage268en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.issn0020-1693en_US
dc.identifier.issn1873-3255en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage264en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2010.09.023
dc.identifier.urihttps://hdl.handle.net/11454/44795
dc.identifier.volume365en_US
dc.identifier.wosWOS:000285624200040en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRhodium-NHC complexesen_US
dc.subjectBenzimidazoleen_US
dc.subjectDiether substituenten_US
dc.subjectTransfer hydrogenationen_US
dc.titleDiether functionalized rhodium(I)-N-heterocyclic carbene complexes and their catalytic application for transfer hydrogenation reactionsen_US
dc.typeArticleen_US

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