Synthesis of new imidazole-based monomer and copolymerization studies with methyl methacrylate

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dc.contributor.authorYildiz, Murat
dc.contributor.authorAlp, Serap
dc.contributor.authorSaltan, Fehmi
dc.contributor.authorAkat, Hakan
dc.date.accessioned2020-12-01T12:01:37Z
dc.date.available2020-12-01T12:01:37Z
dc.date.issued2020
dc.departmentEge Üniversitesien_US
dc.description.abstractIn this study, copolymers were synthesized using methyl methacrylate (MMA) and 2-allyloxymethyl-1-methylimidazole (AOMMI) monomers at various ratios. For this purpose, hydroxyl end-functionalized imidazole was initially prepared with 1-methylimidazole and then it was used to prepare allyl-derived imidazole monomers. Finally, the synthesis of copolymers (poly(MMA-co-AOMMI)) was carried out using different proportions of commercial MMA and AOMMI monomers. Photopolymerization method was preferred as polymerization technique. the polymerization was carried out in solvent-free medium and benzophenone was used as the initiator. Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance spectroscopy (H-1 NMR and C-13 NMR) and elemental analysis were used for the structural characterization of the obtained copolymers. Molecular weights and the thermal behaviour of the synthesized copolymers were analysed with gel permeation chromatography (GPC) and thermogravimetry (TG) techniques, respectively. the surface of the products was tried to be illuminated using scanning electron microscopy (SEM). According to the obtained FTIR, NMR and elemental analysis results, the copolymers were successfully synthesized. A number average molecular weights of poly(MMA-co-AOMMI) samples were found 13,500 (MMA:2/AOMMI:1), 16,600 (MMA:1/AOMMI:2) and 17,300 (MMA:1/AOMMI:1) according to the mixing ratios. When the thermal stabilities of the synthesized copolymers were observed, it has been seen that those containing imidazole had higher stability than the neat PMMA.en_US
dc.identifier.doi10.1007/s13726-020-00815-7
dc.identifier.endpage523en_US
dc.identifier.issn1026-1265
dc.identifier.issn1735-5265
dc.identifier.issn1026-1265en_US
dc.identifier.issn1735-5265en_US
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85083678069en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage515en_US
dc.identifier.urihttps://doi.org/10.1007/s13726-020-00815-7
dc.identifier.urihttps://hdl.handle.net/11454/62472
dc.identifier.volume29en_US
dc.identifier.wosWOS:000527447100001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofIranian Polymer Journalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectImidazoleen_US
dc.subjectMMAen_US
dc.subjectCopolymerizationen_US
dc.subjectPhotopolymerizationen_US
dc.subjectGreen chemistryen_US
dc.titleSynthesis of new imidazole-based monomer and copolymerization studies with methyl methacrylateen_US
dc.typeArticleen_US

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