Synthesis and characterization of metal carbonyls [M(CO)(6)(M = Cr, Mo, W), Re(CO)(5)Br, Mn(CO)(3)C-P] with 2-hydroxy-1-napthaldehyde ethanesulfonylhydrazone (nafesh)
| dc.contributor.author | Senturk, OS | |
| dc.contributor.author | Sert, S | |
| dc.contributor.author | Ozdemir, U | |
| dc.date.accessioned | 2019-10-27T18:59:01Z | |
| dc.date.available | 2019-10-27T18:59:01Z | |
| dc.date.issued | 2003 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | Five new complexes, M(CO)(5)(nafesh) (M = Cr (1), Mo (2), W (3)), Re(CO)(4)Br(nafesh) (4) and Mn(CO)(3)(nafesh) (5) have been synthesized by the photochemical reaction of metal carbonyls M(CO)(6) (M = Cr, Mo, W), Re(CO)(5)Br, and Mn(CO)(3)CP with 2-hydroxy-1-napthaldehyde ethane-sulfonylhydrazone (nafesh). The complexes have been characterized by elemental analysis, El mass spectrometry, FT-IR, H-1 NMR spectroscopy. The spectroscopic studies show that nafesh behaves as a monodentate ligand coordinating via imine N donor atom in M(CO)(5)(nafesh) (M = Cr, Mo, W) and Re(CO)(4)Br(nafesh) and as tridentate ligand in Mn(CO)(3)(nafesh). | en_US |
| dc.identifier.doi | 10.1515/znb-2003-1115 | |
| dc.identifier.endpage | 1127 | en_US |
| dc.identifier.issn | 0932-0776 | |
| dc.identifier.issn | 0932-0776 | en_US |
| dc.identifier.issue | 11 | en_US |
| dc.identifier.startpage | 1124 | en_US |
| dc.identifier.uri | https://doi.org/10.1515/znb-2003-1115 | |
| dc.identifier.uri | https://hdl.handle.net/11454/37573 | |
| dc.identifier.volume | 58 | en_US |
| dc.identifier.wos | WOS:000188262900015 | en_US |
| dc.identifier.wosquality | Q3 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Verlag Z Naturforsch | en_US |
| dc.relation.ispartof | Zeitschrift Fur Naturforschung Section B-A Journal of Chemical Sciences | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | hydrazone | en_US |
| dc.subject | 2-hydroxy-1-napthaldehyde ethanesulfonylhydrazone | en_US |
| dc.subject | metal carbonyls | en_US |
| dc.title | Synthesis and characterization of metal carbonyls [M(CO)(6)(M = Cr, Mo, W), Re(CO)(5)Br, Mn(CO)(3)C-P] with 2-hydroxy-1-napthaldehyde ethanesulfonylhydrazone (nafesh) | en_US |
| dc.type | Article | en_US |
