Polymeric thermal analysis of C+H and C+H+Ar ion implanted UHMWPE samples

Küçük Resim Yok

Tarih

2007

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Science Bv

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Chemical surface characterization of C + H hybrid ion implanted UHMWPE samples were carried out using DSC (differential scanning calorimeter) and TGA (thermal gravimetric analysis) techniques. Samples were implanted with a fluence of 10(17) ion/cm(2) and an extraction voltage of 30 kV. The study of TGA and DSC curves showed that: (1) Polymeric decomposition temperature increased, (2) T-m, Delta C-p and Delta H-m values changed while Delta C-p and Delta H-m increased. T-g value could not be measured, because of some experimental limitations. However, the increase in Delta H-m values showed that T-g values increased, (3) the branch density which indicated the increase in number of cross-link (M-c) decreased in ion implanted samples and (4) increase in Delta H-m values indicated increase in crystallinity of implanted surface of UHMWPE samples. Published by Elsevier B.V.

Açıklama

19th International Conference on Application of Accelerators in Research and Industry -- AUG 20-25, 2006 -- Ft Worth, TX

Anahtar Kelimeler

heat capacity (Delta C-p), melting temperature (T-m), cross-link, melting enthalpy (Delta H-m), branch, glassy transition temperature (T-g)

Kaynak

Nuclear Instruments & Methods in Physics Research Section B-Beam Interactions With Materials and Atoms

WoS Q Değeri

Q2

Scopus Q Değeri

Cilt

261

Sayı

01.Feb

Künye