Thermal reactions of dimanganese decacarbonyl with tetraalkyldiphosphine disulfides (R = Me, Et, Pr-n, Bu-n) and crystal structure of [Mn-2(CO)(8)(mu-PBu2n)(2)]

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dc.contributor.authorHogarth, G
dc.contributor.authorSarykahya, F
dc.contributor.authorPenturk, OS
dc.date.accessioned2019-10-27T18:18:05Z
dc.date.available2019-10-27T18:18:05Z
dc.date.issued2002
dc.departmentEge Üniversitesien_US
dc.description.abstractReaction of Mn-2(CO)(10) with R2P(S)P(S)R-2 (R = Me, Et, Pr", Bu") in toluene at 120degreesC yields binuclear [Mn-2(CO)(8)(mu-PR2)(2)] and trinuclear [Mn(CO)(3)(mu-S=PR2)](3) complexes. Both result from phosphorus-phosphorus bond scission, while in the former sulfur abstraction has also occurred. An X-ray diffraction study of [Mn-2(CO)(8)(mu-PBu"(2))(2)] confirms that the manganese adopts a distorted octahedral geometry with local C-2v symmetry. (C) 2002 Elsevier Science Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/S0277-5387(02)00843-4
dc.identifier.endpage795en_US
dc.identifier.issn0277-5387
dc.identifier.issn0277-5387en_US
dc.identifier.issue7en_US
dc.identifier.startpage791en_US
dc.identifier.urihttps://doi.org/10.1016/S0277-5387(02)00843-4
dc.identifier.urihttps://hdl.handle.net/11454/35419
dc.identifier.volume21en_US
dc.identifier.wosWOS:000176972200016en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectdiphosphine disulfideen_US
dc.subjectdimanganese decacarbonylen_US
dc.subjectphosphidoen_US
dc.subjectphosphidosulfideen_US
dc.titleThermal reactions of dimanganese decacarbonyl with tetraalkyldiphosphine disulfides (R = Me, Et, Pr-n, Bu-n) and crystal structure of [Mn-2(CO)(8)(mu-PBu2n)(2)]en_US
dc.typeArticleen_US

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