Synthesis and catalytic properties of novel ruthenium N-heterocyclic-carbene complexes

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dc.contributor.authorDemir, Serpil
dc.contributor.authorOezdemir, Ismail
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T21:19:20Z
dc.date.available2019-10-27T21:19:20Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractThe reaction of [RuCl2(p-cymene)](2) with 1,3-dialkylimidazolinium salts 1a-f in the presence of a small excess of cesium carbonate yields chelated eta(6)-arene, eta(1)-carbene ruthenium complexes 2a-f. All synthesised compounds were characterized by elemental analysis, NMR spectroscopy. The catalytic activity of RuCl2(eta(6)-arene, eta(1)-imidazolinylidene) complexes 2a-f was evaluated in the direct arylation of 2-phenylpyridine with chlorobenzene derivatives. (C) 2009 Elsevier B. V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRSTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [[TBAG-U/181 (106T716)]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS [TBAG-U/181 (106T716)], Innou University Research Fund.en_US
dc.identifier.doi10.1016/j.jorganchem.2009.08.030
dc.identifier.endpage4031en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issn0022-328Xen_US
dc.identifier.issn1872-8561en_US
dc.identifier.issue25en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage4025en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2009.08.030
dc.identifier.urihttps://hdl.handle.net/11454/44130
dc.identifier.volume694en_US
dc.identifier.wosWOS:000271099500006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRutheniumen_US
dc.subjectImidazolinium saltsen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectC-H bond activationen_US
dc.subjectArylationen_US
dc.titleSynthesis and catalytic properties of novel ruthenium N-heterocyclic-carbene complexesen_US
dc.typeArticleen_US

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