Thieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cells

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dc.authorscopusid57195630464
dc.authorscopusid57358594600
dc.authorscopusid57216489633
dc.authorscopusid58195617000
dc.authorscopusid54941333900
dc.authorscopusid8379291000
dc.authorscopusid7004084332
dc.contributor.authorIsci, R.
dc.contributor.authorUnal, M.
dc.contributor.authorYesil, T.
dc.contributor.authorEkici, A.
dc.contributor.authorSütay, B.
dc.contributor.authorZafer, C.
dc.contributor.authorOzturk, T.
dc.date.accessioned2024-08-25T18:51:18Z
dc.date.available2024-08-25T18:51:18Z
dc.date.issued2023
dc.departmentEge Üniversitesien_US
dc.description.abstractHeterocyclic compounds have played significant roles in achieving high performance as hole transport materials (HTMs) for perovskite solar cell (PSC) applications. Various studies have focused on the development of fused heterocyclic conjugated structures for hole transport materials. In this report, three novel ?-extended conjugated materials (M1-M3), based on thieno[3,2-b]thiophene (TT) and 4,4?-dimethoxytriphenylamine [TPA(OMe)2], were designed and successfully synthesized via Palladium (0) catalyzed Suzuki coupling reaction. Their optical, electrochemical, and thermal properties were investigated by UV-Vis, fluorescence, cyclic voltammetry, and thermal analysis. The materials were utilized as hole transport materials in p-i-n architecture perovskite solar cells, which displayed performances of open-circuit voltage (Voc) as high as 1,050 mV, a maximum short-circuit current (Jsc) of 16,9 mA/cm2, a maximum fill factor (FF) of 29.3%, and a power conversion efficiency (PCE) of 5.20%. This work demonstrated that thieno[3,2-b]thiophene and TPA(OMe)2-based structures are promising cores for high-performance hole transport materials in perovskite solar cell architecture. Copyright © 2023 Isci, Unal, Yesil, Ekici, Sütay, Zafer and Ozturk.en_US
dc.description.sponsorship100/2000 YOK, 2211A BIDEP/TUBITAK; Ulusal Yüksek Başarımlı Hesaplama Merkezi, Istanbul Teknik Üniversitesi, UHeM: 1010722021; Istanbul Teknik Üniversitesi, IT: 122Z568, 1649B032100473; Sheikh Bahaei National High Performance Computing Center, Isfahan University of Technology, SBNHPCCen_US
dc.description.sponsorshipWe thank the Higher Education Council of Türkiye (YOK) and TUBITAK grants to RI (PhD., 100/2000 YOK and 2211A BIDEP/TUBITAK); ITU (Istanbul Technical University), 122Z568 numbered TUBITAK 1001 Project; TY within the Program nr: 2211/C (Grant nr: 1649B032100473); and Unsped Global Lojistik, Türkiye, for the financial support. The computing resources used in this work were provided by the National Center for High-Performance Computing (UHeM) under grant number 1010722021.en_US
dc.identifier.doi10.3389/fmats.2023.1125462
dc.identifier.issn2296-8016
dc.identifier.scopus2-s2.0-85153473606en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.3389/fmats.2023.1125462
dc.identifier.urihttps://hdl.handle.net/11454/102510
dc.identifier.volume10en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherFrontiers Media S.A.en_US
dc.relation.ispartofFrontiers in Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmz20240825_Gen_US
dc.subjecthole transport materialsen_US
dc.subjectperovskite solar cellen_US
dc.subjectsolution processableen_US
dc.subjectthieno[3,2-b]thiopheneen_US
dc.subjecttriphenylamineen_US
dc.subjectConversion efficiencyen_US
dc.subjectCyclic voltammetryen_US
dc.subjectHole mobilityen_US
dc.subjectOpen circuit voltageen_US
dc.subjectOrganic polymersen_US
dc.subjectPerovskiteen_US
dc.subjectThermoanalysisen_US
dc.subjectThiopheneen_US
dc.subjectConjugated materialsen_US
dc.subjectConjugated structuresen_US
dc.subjectHeterocyclic compounden_US
dc.subjectHole transport materialsen_US
dc.subjectPerformanceen_US
dc.subjectSolar-cell applicationsen_US
dc.subjectSolution processableen_US
dc.subjectSynthesiseden_US
dc.subjectThieno[3,2-b]thiopheneen_US
dc.subjectTriphenylaminesen_US
dc.subjectPerovskite solar cellsen_US
dc.titleThieno[3,2-b]thiophene and triphenylamine-based hole transport materials for perovskite solar cellsen_US
dc.typeArticleen_US

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