Bis{2,6-bis-[1-(4-fluoro-phenyl-imino)-eth-yl]pyridine}- 1?3 N,N',N'';3?3 N,N',N''-di-µ-chlorido-1:2?2 Cl:Cl;2?:3?2 Cl:Cl-trichlorido-1?Cl,2?Cl, 3?Cl-2-copper(I)-1,3-dicopper(II)
Küçük Resim Yok
Tarih
2008
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The title complex, [Cu3Cl5(C21H 17N3F2)2], is the first reported copper trimer including both CuI and CuII ions. The two CuII ions are five-coordinate in a significantly distorted square-pyramidal arrangement, with the bridging Cl atom located in the apical position, and the pyridine (py) N atom, the two imine N atoms and the other Cl atom located in the basal plane. The CuI ion is in a trigonal planar configuration surrounded by three Cl atoms. The structure is stabilized by intra- and inter-molecular C - H?Cl and C - H??(py) hydrogen bonds. © 2008 International Union of Crystallography.
Açıklama
Anahtar Kelimeler
Kaynak
Acta Crystallographica Section C: Crystal Structure Communications
WoS Q Değeri
Scopus Q Değeri
N/A
Cilt
64
Sayı
6
