Preparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)

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dc.contributor.authorUgur F.
dc.contributor.authorŞentürk O.S.
dc.contributor.authorTopaloglu I.
dc.date.accessioned2019-10-27T00:25:49Z
dc.date.available2019-10-27T00:25:49Z
dc.date.issued2000
dc.departmentEge Üniversitesien_US
dc.description.abstractCo2(CO)8 and R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu) react to form the three types of cluster complexes [Co2(µ-CO)(µ4-S)(CO)4]2, (1), [Co4(CO)9(µ3-S)(µ-PR2)2] (2A)-(2D), [(2A), R = Me; (2B), R = Et; (2C), R = n-Pr; (2D), R = n-Bu] and [Co3(CO)7(µ3-S)(SPR2)] (3A)-(3D), [(3A), R = Me; (3B), R = Et; (3C), R = n-Pr; (3D), R = n-Bu]. The structure of (2A) and the disubstituted triphenylphosphine derivative of (3A) were reported previously. The complexes have been characterized by elemental analyses, FT-IR and 31P-[1H] NMR spectroscopy and mass spectrometry.en_US
dc.description.sponsorshipWe thank TUBITAK and the Research Foundation of Ege University for funds and --en_US
dc.identifier.endpage1702en_US
dc.identifier.issn0094-5714
dc.identifier.issn0094-5714en_US
dc.identifier.issue9en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1697en_US
dc.identifier.urihttps://hdl.handle.net/11454/23308
dc.identifier.volume30en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic and Metal-Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.titlePreparation of complexes formed in the reaction between dicobaltoctacarbonyl and tetraalkyldiphosphine disulfides, R2P(S)P(S)R2 (R = Me, Et, n-Pr, n-Bu)en_US
dc.typeArticleen_US

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