Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W), Re(CO)(5)Br, Mn(CO)(3)CP] with 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione (DTTT) and the crystal structure of [W(CO)(5)(DTTT)]
| dc.contributor.author | Sert, S | |
| dc.contributor.author | Ercag, A | |
| dc.contributor.author | Senturk, OS | |
| dc.contributor.author | Sterenberg, BT | |
| dc.contributor.author | Udachin, KA | |
| dc.contributor.author | Ozdemir, U | |
| dc.contributor.author | Sarikahya, FU | |
| dc.date.accessioned | 2019-10-27T18:39:14Z | |
| dc.date.available | 2019-10-27T18:39:14Z | |
| dc.date.issued | 2003 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | Five new complexes, [M(CO)(5)(DTTT)] [M = Cr; 1, Mo; 2, W; 3], [Re(CO)(4)Br(DTTT)] (4) and [Mn(CO)(2)Cp(DTTT)] (5) have been synthesized by the photochemical reaction of metal carbonyls [M(CO)(6)] (M = Cr, Mo and W), [Re(CO)(5)Br], and [Mn(CO)(3)Cp] with 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione (DTTT). The complexes have been characterized by elemental analysis, mass spectrometry, FTIR, H-1 and C-13{H-1} NMR spectroscopy. The spectroscopic studies show that DTTT behaves as a monodentate ligand coordinating via the sulfur (C=S) donor atom in 1-5. An X-ray diffraction study Of [W(CO)(5)(DTTT)] (3) confirms that the tungsten adopts a distorted octahedral geometry with local C-4nu symmetry. (C) 2003 Elsevier Science Ltd. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/S0277(03)00309-7 | |
| dc.identifier.endpage | 1693 | en_US |
| dc.identifier.issn | 0277-5387 | |
| dc.identifier.issn | 0277-5387 | en_US |
| dc.identifier.issue | 13 | en_US |
| dc.identifier.startpage | 1689 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/S0277(03)00309-7 | |
| dc.identifier.uri | https://hdl.handle.net/11454/36735 | |
| dc.identifier.volume | 22 | en_US |
| dc.identifier.wos | WOS:000184113200009 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Pergamon-Elsevier Science Ltd | en_US |
| dc.relation.ispartof | Polyhedron | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | pesticides | en_US |
| dc.subject | antiprotooans | en_US |
| dc.subject | 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione | en_US |
| dc.title | Photochemical reactions of metal carbonyls [M(CO)(6) (M=Cr, Mo, W), Re(CO)(5)Br, Mn(CO)(3)CP] with 3,5-dimethyl-tetrahydro-2H-1,3,5-thiadiazine-2-thione (DTTT) and the crystal structure of [W(CO)(5)(DTTT)] | en_US |
| dc.type | Article | en_US |
