Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions

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dc.contributor.authorKaraca E.Ö.
dc.contributor.authorDehimat Z.I.
dc.contributor.authorYaşar S.
dc.contributor.authorGürbüz N.
dc.contributor.authorTebbani D.
dc.contributor.authorÇetinkaya B.
dc.contributor.authorÖzdemir İ.
dc.date.accessioned2021-05-03T20:56:54Z
dc.date.available2021-05-03T20:56:54Z
dc.date.issued2021
dc.description.abstractThe reaction of [RuCl2(p-cymene)]2 with in situ prepared Ag-N-heterocyclic carbene (NHC) complexes yields a series of [RuCl2(p-cymene)(NHC)] complexes (2). All of the complexes have been characterised by elemental analysis, and 1H NMR and 13C NMR spectroscopies. These complexes have been tested for the N-alkylation of aromatic amines with arylmethyl alcohols under neat conditions in the presence of KOtBu at 120 °C. Compounds (2) are stable and have high catalytic/selective activity for the N-alkylation reactions of primary amines to afford secondary amines. © 2021 Elsevier B.V.en_US
dc.identifier.doi10.1016/j.ica.2021.120294
dc.identifier.issn0020-1693
dc.identifier.issn0020-1693en_US
dc.identifier.scopus2-s2.0-85103301858en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2021.120294
dc.identifier.urihttps://hdl.handle.net/11454/71411
dc.identifier.volume520en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAmineen_US
dc.subjectHydrogen auto-transfer methoden_US
dc.subjectN-alkylationen_US
dc.subjectRu(II)-NHCen_US
dc.titleRu(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditionsen_US
dc.typeArticleen_US

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