1-(1H-Benzimidazol-1-ylmeth-yl)-3-[2-(di-isopropyl-amino)eth-yl] -1H-benzimid-azolium bromide 0.25-hydrate
| dc.contributor.author | Arslan H. | |
| dc.contributor.author | VanDerveer D. | |
| dc.contributor.author | Demir S. | |
| dc.contributor.author | Zdemir S. | |
| dc.contributor.author | Cetinkaya B. | |
| dc.date.accessioned | 2019-10-27T08:35:52Z | |
| dc.date.available | 2019-10-27T08:35:52Z | |
| dc.date.issued | 2009 | |
| dc.department | Ege Üniversitesi | en_US |
| dc.description.abstract | The title N-heterocyclic carbene derivative, C23H 30N5+·Br-·0.25H2O, was synthesized using microwave heating and was characterized by 1H and 13C NMR spectroscopy and a single-crystal X-ray diffraction study. The structure of the title compound are stabilized by a network of intra- and inter-molecular C - H?Br hydrogen-bonding inter-actions. The crystal structure is further stabilized by ?-? stacking inter-actions between benzene and imidazole fragment rings of parallel benzo[d]imidazole rings, with a separation of 3.486 (3) Å between the centroids of the benzene and imidazole rings. There is also an inter-molecular C - H?? inter-action in the crystal structure. The C - N bond lengths for the central benzimidazole ring are shorter than the average single C - N bond, thus showing varying degrees of double-bond character and indicating partial electron delocalization within the C - N - C - N - C fragment. The isopropyl group is disordered over two sites with occupancies of 0.792 (10) and 0.208 (10). © 2009. | en_US |
| dc.identifier.doi | 10.1107/S160053680900765X | |
| dc.identifier.endpage | o700 | en_US |
| dc.identifier.issn | 1600-5368 | |
| dc.identifier.issn | 1600-5368 | en_US |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.scopusquality | N/A | en_US |
| dc.identifier.startpage | o699 | en_US |
| dc.identifier.uri | https://doi.org/10.1107/S160053680900765X | |
| dc.identifier.uri | https://hdl.handle.net/11454/27308 | |
| dc.identifier.volume | 65 | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.title | 1-(1H-Benzimidazol-1-ylmeth-yl)-3-[2-(di-isopropyl-amino)eth-yl] -1H-benzimid-azolium bromide 0.25-hydrate | en_US |
| dc.type | Article | en_US |
