Nanocomposites Based on Crosslinked Polyacrylic Latex/Silver Nanoparticles for Waterborne High-Performance Antibacterial Coatings

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dc.contributor.authorYilmaz, Onur
dc.contributor.authorKaresoja, Mikko
dc.contributor.authorAdiguzel, A. Candas
dc.contributor.authorZengin, Gokhan
dc.contributor.authorTenhu, Heikki
dc.date.accessioned2019-10-27T22:15:02Z
dc.date.available2019-10-27T22:15:02Z
dc.date.issued2014
dc.departmentEge Üniversitesien_US
dc.description.abstractFunctional polymer/AgNPs nanocomposites have been prepared. Silver nanoparticles (NPs) were synthesized to which polyacrylamide, PAAm, was covalently bound. PAAm was synthesized via a RAFT reaction and carried thiol and carboxylic acid end groups. Thiol was used to bind the polymer to the metal surface and carboxyl for further reactions. The AgNPs were used in a post-crosslinking reaction with a separately synthesized poly(butyl acrylate-co-methyl methacrylate)/polyglycidyl methacrylate core/shell latex bearing epoxy functional groups. Dynamic mechanical analysis showed that the functional AgNPs effectively crosslinked the latex polymer, and that the final product had excellent mechanical strength. Antibacterial tests revealed that the nanocomposite films had strong antibacterial activity against all types of the bacteria and the immobilization of silver NPs by crosslinking retarded the release of silver in comparison to the uncrosslinked ones. With the presented method, it is possible to obtain ductile antibacterial nanocomposites to be used as waterborne functional coatings. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1435-1447en_US
dc.description.sponsorshipCouncil of Higher Education (YOK) of TurkeyMinistry of National Education - Turkeyen_US
dc.description.sponsorshipThe authors thank to the Council of Higher Education (YOK) of Turkey for the support to the research.en_US
dc.identifier.doi10.1002/pola.27130
dc.identifier.endpage1447en_US
dc.identifier.issn0887-624X
dc.identifier.issn1099-0518
dc.identifier.issn0887-624Xen_US
dc.identifier.issn1099-0518en_US
dc.identifier.issue10en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1435en_US
dc.identifier.urihttps://doi.org/10.1002/pola.27130
dc.identifier.urihttps://hdl.handle.net/11454/50108
dc.identifier.volume52en_US
dc.identifier.wosWOS:000333678300009en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofJournal of Polymer Science Part A-Polymer Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectantibacterialen_US
dc.subjectcoatingsen_US
dc.subjectcrosslinkingen_US
dc.subjecthigh performance polymersen_US
dc.subjectnanocompositesen_US
dc.subjectsilver nanoparticlesen_US
dc.titleNanocomposites Based on Crosslinked Polyacrylic Latex/Silver Nanoparticles for Waterborne High-Performance Antibacterial Coatingsen_US
dc.typeArticleen_US

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