Thermogravimetric Study of Ionic Pt(II) Complexes Containing Bis(diphenylthiophosphinyl)methane

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dc.contributor.authorDogan, F.
dc.contributor.authorIrisli, S.
dc.date.accessioned2019-10-27T20:21:39Z
dc.date.available2019-10-27T20:21:39Z
dc.date.issued2009
dc.departmentEge Üniversitesien_US
dc.description.abstractThe TG-DTG and DTA study of dipositive platinum(II)complexes of the general formula [Pt(L-L)(dppmS(2))](ClO(4))(2), where dppmS(2) = Ph(2)P(S)CH(2)P(S)Ph(2) and L-L = dppm (Ph(2)PCH(2)PPh(2)), dppe (Ph(2)PCH(2)CH(2)PPh(2)), and dppp (Ph(2)PCH(2)CH(2)CH(2)PPh(2)), were studied by thermogravimetric analysis from ambient temperature to 1000 degrees C in nitrogen atmosphere. The decomposition occurred in one stage for [Pt(L-L)dppmS(2)](ClO(4))(2), [Pt(L-L)dpppS(2)](ClO(4))(2) and [Pt(L-L)dppmS(2)](ClO(4))(2) complexes. The values of activation energy, E, frequency factor, A, reaction order, n, entropy change, Delta S(not equal), enthalpy change, Delta H(not equal), and Gibss free energy change, Delta G(not equal), of the thermal decomposition were calculated by means of Coats-Redfern method (CR), MacCallum-Tanner method (MC) and van Krevelen method (vK). The activation energy values obtained by CR, MC and vK methods were in good agreement with each other.en_US
dc.identifier.endpage6en_US
dc.identifier.issn0137-5083
dc.identifier.issue1en_US
dc.identifier.startpage1en_US
dc.identifier.urihttps://hdl.handle.net/11454/41790
dc.identifier.volume83en_US
dc.identifier.wosWOS:000263044000001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherPolish Chemical Socen_US
dc.relation.ispartofPolish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectthermal behaviouren_US
dc.subjectionic Pt(II) complexesen_US
dc.subjectactivation energyen_US
dc.titleThermogravimetric Study of Ionic Pt(II) Complexes Containing Bis(diphenylthiophosphinyl)methaneen_US
dc.typeArticleen_US

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