Hetero- and homo-leptic Ru(II) catalyzed synthesis of cyclic carbonates from CO2; Synthesis, spectroscopic characterization and electrochemical properties

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dc.contributor.authorKilic, Ahmet
dc.contributor.authorUlusoy, Mahmut
dc.contributor.authorDurgun, Mustafa
dc.contributor.authorTasci, Zeynep
dc.contributor.authorYilmaz, Ismail
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T21:16:57Z
dc.date.available2019-10-27T21:16:57Z
dc.date.issued2010
dc.departmentEge Üniversitesien_US
dc.description.abstractBased on the a ligand BDPPZ [(9a,13a-dihydro-4,5,9,14-tetraaza-benzo[b]triphenylene-11-yl)-phenyl-methanone] (1) and its polypyridyl hetero- and homoleptic Ru(II) metal complexes, [Ru(bpy)(2)L](PF6)(2) (2), [Ru(phen)(2)L](PF6)(2) (3), [Ru(dafo)(2)L](PF6)(2) (4), [Ru(dcbpy)(2)L](PF6)(2) (5) and (RuL3)(PF6)(2) (6) (where, L = ligand, bpy = 2,2'-bipyridine, phen = 1,10-phenantroline, dafo = 4,5-diazafluoren-9-one and dcbpy = 3,3'-dicarboxy-2,2'-bipyridine), have been synthesized and characterized by elemental analysis, UV-vis, FT-IR, H-1 and C-13-NMR spectra (for ligand), molar conductivity measurements and X-ray powder techniques. The electrochemical parameters of the substituted ligand and its polypyridyl hetero- and homoleptic Ru(II) metal complexes are reported by cyclic voltammetry. UV-vis spectroscopy is used to compare the differences between the conjugated 7 systems in this ligand and its Ru(II) metal complexes. The polypyridyl hetero- and homoleptic Ru(II) metal complexes also tested as catalysts for the formation of cyclic organic carbonates from carbon dioxide and liquid epoxides which served as both reactant and solvent. The results showed that the (Ru(L)(3))(PF6)(2) (6) complex is more efficient than the other Ru(II) complexes for the formation of cyclic organic carbonates from carbon dioxide. Copyright (C) 2010 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipHarran University (Sanliurfa, Turkey)Harran Universityen_US
dc.description.sponsorshipThis work was supported, in part, by the Research Fund of Harran University (Sanliurfa, Turkey).en_US
dc.identifier.doi10.1002/aoc.1638
dc.identifier.endpage453en_US
dc.identifier.issn0268-2605
dc.identifier.issue6en_US
dc.identifier.startpage446en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1638
dc.identifier.urihttps://hdl.handle.net/11454/43748
dc.identifier.volume24en_US
dc.identifier.wosWOS:000278352200003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRu(II) complexesen_US
dc.subjectcatalystsen_US
dc.subjectcarbon dioxideen_US
dc.subjectcyclic carbonateen_US
dc.titleHetero- and homo-leptic Ru(II) catalyzed synthesis of cyclic carbonates from CO2; Synthesis, spectroscopic characterization and electrochemical propertiesen_US
dc.typeArticleen_US

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