Mono- and binuclear ruthenium(II) complexes containing pyridine-2,6-diimine (Pydim) ligands: Synthesis, characterization and catalytic activity in the transfer hydrogenation of acetophenone

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dc.contributor.authorDayan, Osman
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2019-10-27T19:33:52Z
dc.date.available2019-10-27T19:33:52Z
dc.date.issued2007
dc.departmentEge Üniversitesien_US
dc.description.abstractA series of neutral mono- and binuclear Ru(II) complexes: [PydimCl(2)RuL] (Pydim (1) pyridine-2,6-diimine; (2) L = NCMe; (3) L = PPh3) and [PydimCl(2)Ru(L-L)RuCl(2)Pydim] (4) L-L = pyrazine; (5) L-L = 4,4'-bipyridine) have been synthesized from the corresponding (p-cymene)ruthenium dichloride dimer, pydim and ancillary ligands L and L-L, respectively. The Pydim-Ru(II) complexes have been employed as catalysts for the transfer hydrogenation of acetophenone in the presence of KOH using 2-propanol as a hydrogen source. Ligand substitution studies indicate that there is a significant difference in reactivity between complexes containing L/L-L and Pydim. Yields of up to 93% were obtained after 5 min at 82 degrees C. (C) 2007 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molcata.2007.02.026
dc.identifier.endpage141en_US
dc.identifier.issn1381-1169
dc.identifier.issn1381-1169en_US
dc.identifier.issue01.Feben_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage134en_US
dc.identifier.urihttps://doi.org/10.1016/j.molcata.2007.02.026
dc.identifier.urihttps://hdl.handle.net/11454/39540
dc.identifier.volume271en_US
dc.identifier.wosWOS:000246908500023en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Molecular Catalysis A-Chemicalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjecttridentate triamine ligandsen_US
dc.subjectpyridine-2,6-diiminesen_US
dc.subjectRu(II) complexesen_US
dc.subjecttransfer hydrogenation of acetophenoneen_US
dc.titleMono- and binuclear ruthenium(II) complexes containing pyridine-2,6-diimine (Pydim) ligands: Synthesis, characterization and catalytic activity in the transfer hydrogenation of acetophenoneen_US
dc.typeArticleen_US

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