Preparation and crystallographic characterization of Pd(II) complexes containing imidobis(diphenylthiophosphinato) ligand

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dc.contributor.authorYanar, Selmin
dc.contributor.authorIrisli, Sevil
dc.contributor.authorBueyuekguengoer, Orhan
dc.date.accessioned2019-10-27T20:01:55Z
dc.date.available2019-10-27T20:01:55Z
dc.date.issued2007
dc.departmentEge Üniversitesien_US
dc.description.abstractThe reactions of PdCl2(L-L) [L-L = Ph2PCH2PPh2(dppm), Ph2PCH2CH2PPh2(dppe) and Ph2PCH2CH2CH2PPh2(dppp)] with equivalent amount of (Ph2P(S)NHP(S)Ph-2)(dppaS(2)) gave the complexes [Pd(L-L)(dppaS(2)-H)]ClO4 [L-L = dppm (1), dppe (2), dppp (3)]. The different synthetic route was used for complex 2 by using of Pd(dppe)Cl-2 and K[N(PSPh2)(2)] as starting materials (2a). All of these complexes have been characterized P-31{H-1} NMR, IR and elemental analyses. The complexes 2, 2a and 3 were crystallographically characterized. The coordination geometry around the Pd atoms in these complexes distorted square planar. Six membered dppaS2-H rings are twist boat conformations in three complexes. (C) 2007 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2007.05.007
dc.identifier.endpage4118en_US
dc.identifier.issn0277-5387
dc.identifier.issn0277-5387en_US
dc.identifier.issue15en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage4114en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2007.05.007
dc.identifier.urihttps://hdl.handle.net/11454/41299
dc.identifier.volume26en_US
dc.identifier.wosWOS:000249905900011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectpalladium complexesen_US
dc.subjectX-ray crystal structuresen_US
dc.subjectPhosphinesen_US
dc.subjectphosphine complexesen_US
dc.subjectdiphosphinesen_US
dc.subjectchalcogenide ligandsen_US
dc.titlePreparation and crystallographic characterization of Pd(II) complexes containing imidobis(diphenylthiophosphinato) liganden_US
dc.typeArticleen_US

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