Reactivity of inorganic anion exchanger BiPbO2(NO3) with fluoride ions in solution

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dc.contributor.authorKodama, H
dc.contributor.authorKabay, N
dc.date.accessioned2019-10-27T18:20:32Z
dc.date.available2019-10-27T18:20:32Z
dc.date.issued2001
dc.departmentEge Üniversitesien_US
dc.descriptionXIVth International Symposium on the Reactivity of Solids (XIVth ISRS) -- AUG 27-31, 2000 -- BUDAPEST, HUNGARYen_US
dc.description.abstractIn this study, we investigated the reactivity of BiPbO2(NO3) with aqueous fluoride ions. Although BiPbO2(NO3) is known to react very well with iodide or chloride ions in aqueous solution at and near pH 1 or 13, the reaction of BiPbO2(NO,) with fluoride ions has not been studied. The experimental result in the present study shows that fluoride ions reacted in solution at pH 1, but did not react at pH 6.5 or 13. The result at pH 13 differs from that of the other halide ions. It may be possible to use this difference to separate fluoride ions from other halide ions. Selectivity tests for F-I mixed solution and F-Cl mixed solution were carried out and gave the expected results. The reaction mechanism of BiPbO2(NO,) with fluoride ions at pH 1 was studied in solution where the NO3-1 was not exchanged with a fluoride ion; however, BiPbO2(NO3) decomposed producing bismuth oxide fluoride (beta -phase). (C) 2001 Elsevier Science B.V. All rights reserved.en_US
dc.description.sponsorshipMol Rt Downstream Business Grp, Inst Environm Protect, Fdn Technol Progress Ind, Minist Educ, Deputy State Secretary Higher Educ & Sci, OMFB, Natl Comm Technol Dev, OTKA, NAtl Fdn Sci & Res, Off Int Cooperat Hungarian Acad Sci, Off Press, Szegeden_US
dc.identifier.doi10.1016/S0167-2738(01)00775-5
dc.identifier.endpage607en_US
dc.identifier.issn0167-2738
dc.identifier.issn0167-2738en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage603en_US
dc.identifier.urihttps://doi.org/10.1016/S0167-2738(01)00775-5
dc.identifier.urihttps://hdl.handle.net/11454/35804
dc.identifier.volume141en_US
dc.identifier.wosWOS:000169421800085en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofSolid State Ionicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBiPbO2(NO3)en_US
dc.subjectfuoride ionen_US
dc.subjectbismuth oxide fluoride (beta-phase)en_US
dc.subjectinorganic ion exchangeren_US
dc.subjection exchangeen_US
dc.subjectselective reactionen_US
dc.titleReactivity of inorganic anion exchanger BiPbO2(NO3) with fluoride ions in solutionen_US
dc.typeArticleen_US

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