Ru(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditions

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dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorDehimat, Zieneb Imene
dc.contributor.authorYasar, Sedat
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorTebbani, Dahmane
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2023-01-12T19:54:56Z
dc.date.available2023-01-12T19:54:56Z
dc.date.issued2021
dc.departmentN/A/Departmenten_US
dc.description.abstractThe reaction of [RuCl2(p-cymene)]2 with in situ prepared Ag-N-heterocyclic carbene (NHC) complexes yields a series of [RuCl2(p-cymene)(NHC)] complexes (2). All of the complexes have been characterised by elemental analysis, and 1H NMR and 13C NMR spectroscopies. These complexes have been tested for the N-alkylation of aromatic amines with arylmethyl alcohols under neat conditions in the presence of KOtBu at 120 ?C. Compounds (2) are stable and have high catalytic/selective activity for the N-alkylation reactions of primary amines to afford secondary amines.en_US
dc.identifier.doi10.1016/j.ica.2021.120294
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.issn0020-1693en_US
dc.identifier.issn1873-3255en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2021.120294
dc.identifier.urihttps://hdl.handle.net/11454/76575
dc.identifier.volume520en_US
dc.identifier.wosWOS:000647788800007en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAmineen_US
dc.subjectHydrogen auto-transfer methoden_US
dc.subjectN-alkylationen_US
dc.subjectRu(II)-NHCen_US
dc.subjectRuthenium Ii Complexesen_US
dc.subjectHeterocyclic-Carbeneen_US
dc.subjectBorrowing Hydrogenen_US
dc.subjectEfficient Catalystsen_US
dc.subjectIntramolecular Hydroaminationen_US
dc.subjectReductive Aminationen_US
dc.subjectOlefin Metathesisen_US
dc.subjectPincer Complexesen_US
dc.subjectHighly Efficienten_US
dc.subjectAromatic-Aminesen_US
dc.titleRu(II)-NHC catalysed N-Alkylation of amines with alcohols under solvent-free conditionsen_US
dc.typeArticleen_US

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